Citation: Huihuang Chen, Jiangang Ku, Lianzhou Wang. Thermal catalysis under dark ambient conditions in environmental remediation: Fundamental principles, development, and challenges[J]. Chinese Journal of Catalysis, ;2019, 40(8): 1117-1134. doi: S1872-2067(19)63366-8 shu

Thermal catalysis under dark ambient conditions in environmental remediation: Fundamental principles, development, and challenges

a University of Science and Technology of China, Hefei National Laboratory for Physical Sciences at the Microscale, Hefei 230026, Anhui, China;
b School of Zijin Mining, Fuzhou University, Fuzhou 350108, Fujian, China;
c The University of Queensland, School of Chemical Engineering, Brisbane Qld 4072, Australia

Received Date: 1 December 2018
Revised Date: 26 March 2019

Fund Project: H. Chen gratefully acknowledges the China Scholarship Council and gives special thanks to the facilities, scientific and technical assistance from the University of Queensland and the help from Prof. Joe da Costa. The authors acknowledge funding support by the National Natural Science Foundation of China (51674091, 51104048).

Thermal catalytic degradation of organic pollutants conducted in the dark at room temperature under atmospheric pressure without the need of external chemicals and energy sources has attracted a lot of attention over the last two decades. It provides unparalleled advantages over other advanced oxidation processes (AOPs) in treating domestic and industrial contaminated wastewater from the viewpoint of energy/chemical conservation and ease of operation. Rich knowledge has been accumulated in terms of the synthesis and application of thermal catalysts though controversies remain regarding their underlying mechanisms. This review sheds light on the proposed thermo-catalysis mechanism for the first time and presents the development of thermal catalysts under dark ambient conditions with a focus on catalyst materials, catalytic activity, and mechanism. The present review aims to provide mechanistic insights into the rational design of novel and efficient catalysts, and their underlying mechanisms as well as the emerging challenges and perspectives in thermo-catalysis under dark ambient conditions used for the practical and efficient treatment of contaminated wastewater.
- Thermal catalysis under dark ambient conditions,
- Mechanisms,
- Advanced oxidation processes,
- Wastewater treatment,
- Organic pollutant degradation
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