Citation: Xiaoshan Zhang, Ning Rui, Xinyu Jia, Xue Hu, Chang-jun Liu. Effect of decomposition of catalyst precursor on Ni/CeO₂ activity for CO methanation[J]. Chinese Journal of Catalysis, ;2019, 40(4): 495-503. doi: S1872-2067(19)63289-4 shu

Effect of decomposition of catalyst precursor on Ni/CeO₂ activity for CO methanation

Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Received Date: 20 October 2018
Revised Date: 25 December 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21476157, 21536008 and 21621004), and the National Key R&D Program of China (2016YFB0600902).

CO methanation on Ni/CeO₂ has recently received increasing attention. However, the low-temperature activity and carbon resistance of Ni/CeO₂ still need to be improved. In this study, plasma decomposition of nickel nitrate was performed at ca. 150℃ and atmospheric pressure. This was followed by hydrogen reduction at 500℃ in the absence of plasma, and a highly dispersed Ni/CeO₂ catalyst was obtained with improved CO adsorption and enhanced metal-support interaction. The plasma-decomposed catalyst showed significantly improved low-temperature activity with high methane selectivity (up to 100%) and enhanced carbon resistance for CO methanation. For example, at 250℃, the plasma-decomposed catalyst showed a CO conversion of 96.8% with high methane selectivity (almost 100%), whereas the CO conversion was only 14.7% for a thermally decomposed catalyst.
- Nickel,
- CeO₂,
- Carbon monoxide,
- Syngas,
- Methanation,
- Plasma
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
1. [1]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
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7. [7]
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9. [9]
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10. [10]
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  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
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15. [15]
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Effect of decomposition of catalyst precursor on Ni/CeO2 activity for CO methanation

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Effect of decomposition of catalyst precursor on Ni/CeO₂ activity for CO methanation