Citation: Shi Dunfa, Wang Lu, Xia Chungu, Liu Chao. Recent Advances in Visible-Light-Promoted Transformation of Alkyl Boron Compounds[J]. Chinese Journal of Organic Chemistry, ;2020, 40(11): 3605-3619. doi: 10.6023/cjoc202006033 shu

Recent Advances in Visible-Light-Promoted Transformation of Alkyl Boron Compounds

Shi Dunfa ^a,b ,
Wang Lu ^a ,
Xia Chungu ^a ,
Liu Chao ^a,,

a.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Liu Chao, chaoliu@licp.cas.cn
Received Date: 18 June 2020
Revised Date: 29 August 2020
Available Online: 8 September 2020
Fund Project: National Natural Science Foundation of China 21673261National Natural Science Foundation of China 91745110National Natural Science Foundation of China 21872156Natural Science Foundation of Jiangsu Province BK20181194Youth Innovation Promotion Association of the Chinese Academy of Sciences 2018458Project supported by the National Natural Science Foundation of China (Nos. 21673261, 91745110, 21872156), the Natural Science Foundation of Jiangsu Province (Nos. BK20190002, BK20181194) and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (No. 2018458)Natural Science Foundation of Jiangsu Province BK20190002

Figures(31)

Organoboron compounds are valuable synthetic intermediates and widely used in the synthesis of medicine, pesticide and organic optoelectronic materials due to their extensive resouce and highly transformable ability. Among various organoboron compounds, the synthesis and transformation of alkylboron compounds have attracted much attention. As a sustainable and green energy, visible light shows an important effect in organic systhesis. Tetracoordinated alkylboron compounds could occur single electron transfer (SET) process to generate alkyl radical for further transformations. Herein, the recent advances in the photoinduced transformation of alkyl boron compounds are summarized.
- boron,
- photocatalysis,
- radical,
- single electron transfer
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