Citation: Chen Demao, Sun Yuanyuan, Dong Daoqing, Han Qingqing, Wang Zuli. Visible-Light Induced Sulfonylation of Nitroolefins for the Synthesis of Vinyl Sulfones under Photocatalyst Free Conditions[J]. Chinese Journal of Organic Chemistry, ;2020, 40(12): 4267-4273. doi: 10.6023/cjoc202006025 shu

Visible-Light Induced Sulfonylation of Nitroolefins for the Synthesis of Vinyl Sulfones under Photocatalyst Free Conditions

College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, Shandong 266109

Corresponding author: Wang Zuli, wangzulichem@163.com

^†

Received Date: 15 June 2020
Revised Date: 29 July 2020
Available Online: 5 August 2020
Fund Project: the National Natural Science Foundation of China 21772107the Key Research and Development Plan of Shandong Province 2019GSF108017Project supported by the National Natural Science Foundation of China (No. 21772107), and the Key Research and Development Plan of Shandong Province (No. 2019GSF108017)

Figures(4)

An eco-friendly visible light-induced approach for the synthesis of vinyl sulfones from the reaction of nitroolefins with sulfinic acid under photocatalyst free conditions was developed. Simple operation, mild reaction conditions, broad substrate scope and good yields of the desired products made this transformation have an excellent prospect. The anti-microbial activity test showed that some of the desired products had moderate inhibitory rate against V. mali and C. glecosporioides.
- visible light,
- vinyl sulfones,
- nitroolefins,
- sulfinic acid
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