Citation: Li Ying, Ma Zhiqiang, Xu Xuetao. Application of tert-Butanesulfinamide in Total Synthesis of Natural Products[J]. Chinese Journal of Organic Chemistry, ;2020, 40(12): 3991-4014. doi: 10.6023/cjoc202006024 shu

Application of tert-Butanesulfinamide in Total Synthesis of Natural Products

Li Ying ^a ,
Ma Zhiqiang ^a,b,, ,
Xu Xuetao ^a,,

a.
School of Biotechnology and Health Science, Wuyi University, Jiangmen, Guangdong 529020
b.
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510641

Corresponding author: Ma Zhiqiang, cezqma@scut.edu.cn Xu Xuetao, wyuchemxxt@126.com
Received Date: 15 June 2020
Revised Date: 23 July 2020
Available Online: 30 July 2020
Fund Project: Project supported by the Department of Education of Guangdong Province (No. 2019KZDXM035)the Department of Education of Guangdong Province 2019KZDXM035

Figures(35)

The formation of chiral amine intermediates with chiral tert-butanesulfinamide and their applications in asymmetric natural product synthesis in recent years are summarized. tert-Butanesulfinamide has attracted wide attention from chemists because it is stable, commercially available with reasonable price, ease to use, and usually induces high diastereoselectivity in the reactions involved. This review is divided into two sections, including the addition of nucleophiles to tert-butanesulfinyl imide and the addition of tert-butanesulfinyl metal enamine to electrophiles.
- tert-butanesulfinamide,
- chiral amine,
- total synthesis
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