Citation: Ma Xuelin, Han Limin, Zhang Xiaoyong, Hao Zhanzhong, Yang Wei, Zhang Yuheng, Wang Li. A Highly Stable Multi-response Zirconium(Ⅳ) Metal-Organic Frameworks for Fluorescence Sensing of Fe³⁺, Cr₂O₇^2- and Organic Small Molecules[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2938-2948. doi: 10.6023/cjoc202005010 shu

A Highly Stable Multi-response Zirconium(Ⅳ) Metal-Organic Frameworks for Fluorescence Sensing of Fe³⁺, Cr₂O₇^2- and Organic Small Molecules

Ma Xuelin ^a,b ,
Han Limin ^a,, ,
Zhang Xiaoyong ^b,, ,
Hao Zhanzhong ^b ,
Yang Wei ^b ,
Zhang Yuheng ^b ,
Wang Li ^b

a.
Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051
b.
Department of Chemistry, Baotou Teachers'College, Baotou, Inner Mongolia 014030

Corresponding author: Han Limin, hanlimin@imut.edu.cn Zhang Xiaoyong, 66123@bttc.edu.cn
Received Date: 5 May 2020
Revised Date: 1 July 2020
Available Online: 15 July 2020
Fund Project: Project supported by the National Natural Science Foundation of China (No. 51964041), the Natural Science Foundation of Inner Mongolia (Nos. 2018BS02009, 2019MS02031), the Education Department Project of Inner Mongolia (No. NJZY19187), and the Young Innovative Talents in Baotou City (No. 30324001)the Young Innovative Talents in Baotou City 30324001the Natural Science Foundation of Inner Mongolia 2019MS02031the Natural Science Foundation of Inner Mongolia 2018BS02009the Education Department Project of Inner Mongolia NJZY19187the National Natural Science Foundation of China 51964041

Figures(12)

A new zirconium(Ⅳ) metal-organic framework (Zr-MOF) based on tricarboxylate ligands, namely ZrL▪2H₂O (L=2, 2', 2''-([1, 3, 5]-triazine-2, 4, 6-triimino)tribenzoic acid)) has been designed and synthesized. It can be served as a platform of multi-responsive fluorescence sensor for Fe³⁺ and Cr₂O₇^2- in water. The Stern-Volmer constants (K_SV) are 9.54×10⁴, 1.75×10⁴ L·mol^-1, and the limits of detection are 3.78×10^-8, 9.12×10^-7 mol/L, respectively. Meanwhile, it can also be used as a multi-response fluorescence probe to detect acetone, CCl₄ and xylene in N, N-dimethylformamide (DMF) solution. The Stern-Volmer constants (K_SV) are 6534.3, 4325.7, 4025.1 mL^-1, and the limits of detection are 1.09×10^-6, 2.73×10^-5, 3.17×10^-5 mL, respectively. The Zr-MOF was characterized by FTIR, ¹H NMR, powder X-ray diffraction (PXRD), thermo gravimetric analysis (TGA) and elemental analysis. Interestingly, the Zr-MOF has the high water stability and pH stability, but its fluorescence intensity will show certain change law in the range of pH 0~14. Water and urine sample application test showed that Zr-MOF had high sensitive detection for Fe³⁺, and simulated organic solvents test showed that Zr-MOF has high sensitivity and selectivity to acetone, CCl₄ and xylene.
- Zr-MOF,
- fluorescence sensor,
- Fe³⁺,
- Cr₂O₇^2-,
- acetone,
- CCl₄,
- xylene
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A Highly Stable Multi-response Zirconium(Ⅳ) Metal-Organic Frameworks for Fluorescence Sensing of Fe3+, Cr2O72- and Organic Small Molecules

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通讯作者: 陈斌, bchen63@163.com

A Highly Stable Multi-response Zirconium(Ⅳ) Metal-Organic Frameworks for Fluorescence Sensing of Fe³⁺, Cr₂O₇^2- and Organic Small Molecules