Citation: Chen Kaihong, Li Hongru, He Liangnian. Advance and Prospective on CO₂ Activation and Transformation Strategy[J]. Chinese Journal of Organic Chemistry, ;2020, 40(8): 2195-2207. doi: 10.6023/cjoc202004030 shu

Advance and Prospective on CO₂ Activation and Transformation Strategy

a.
State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071
b.
College of Pharmacy, Nankai University, Tianjin 300353

Corresponding author: He Liangnian, heln@nankai.edu.cn
Received Date: 19 April 2020
Revised Date: 22 May 2020
Available Online: 29 May 2020
Fund Project: the China Postdoctoral Science Foundation 2018M641624Project supported by the National Natural Science Foundation of China (No. 21975135) and the China Postdoctoral Science Foundation (No. 2018M641624)the National Natural Science Foundation of China 21975135

Figures(23)

Climate change and depletion of fossil fuels have drawn considerable attention. Considering carbon dioxide is both the dominant greenhouse gas and renewable C₁ source, CO₂ valorization into valuable chemicals is considered to reconcile the environment benefit and sustainable chemistry development. Unfortunately, the thermodynamic stability and kinetic inertness of CO₂ make its chemical transformation challenging. As a consequence, developing highly efficient catalytic systems and synthetic protocols is crucial for CO₂ conversion. In recent years, He's group made great progress on strategy design and catalyst development for CO₂ conversion. A series novel CO₂ conversion strategies are proposed, including CO₂ capture and in-situ transformation, hierarchical reductive functionalization of CO₂, designing thermodynamically favorable reactions by multi-component cascade reaction and photo-promoted CO₂ transformation. Concurrently, the corresponding highly efficient catalytic systems were also developed based on the reaction mechanism and thus CO₂ transformation was successfully performed under mild conditions. It is hoped that this review can arouse broad concern on CO₂ transformation and spur its further development.
- carbon dioxide,
- capture,
- transformation,
- reduction,
- cascade reaction,
- photocatalysis,
- sustainable chemistry,
- synthetic method
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Advance and Prospective on CO₂ Activation and Transformation Strategy