Citation: Liu Yingjie, Li Chen, Meng Jianping, Song Dongxue, Liu Bing, Xu Ying. Recent Progress in Monofluoromethylation[J]. Chinese Journal of Organic Chemistry, ;2020, 40(8): 2322-2337. doi: 10.6023/cjoc202003055 shu

Recent Progress in Monofluoromethylation

School of Pharmacy, Harbin University of Commerce, Harbin 150076

Corresponding author: Liu Yingjie, liuyj691@nenu.edu.cn
Received Date: 24 March 2020
Revised Date: 25 April 2020
Available Online: 15 May 2020
Fund Project: Outstanding Youth Project of Natural Science Foundation of Heilongjiang Province YQ2019B004Youth Innovation Talent Project of Harbin University of Commerce 2016QN056Youth Reserve Talent Program of Harbin University of Commerce 2019CX36Project supported by the Outstanding Youth Project of Natural Science Foundation of Heilongjiang Province (No. YQ2019B004) and the Youth Innovation Talent Project of Harbin University of Commerce (No. 2016QN056) and the Youth Reserve Talent Program of Harbin University of Commerce (No. 2019CX36)

Figures(51)

Organic fluorides play an indispensable role in medicine, agricultural chemistry and other fields, among them fluoromethyl functional groups have strong lipophilicity, which can greatly improve the pharmacokinetics properties of drug molecules. Therefore, it is of great value to develop various fluorination reactions, especially to introduce monofluoromethyl into molecules in fluorination chemistry. The research progress of the monofluoromethylation of different structural molecules is summarized according to the classification of fluoromethyl reagents, and the possible mechanism of some reactions is discussed.
- organic fluoride,
- fluoromethyl functional group,
- fluoromethyl reagent,
- monofluoromethylation reaction
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