Citation: Cong Yikang, Zeng Xianghua. Nano Cu-CuFe₂O₄-Catalyzed Selective Reduction of α, β, γ, δ-Unsaturated Carbonyls in Alcohol Medium[J]. Chinese Journal of Organic Chemistry, ;2020, 40(8): 2411-2418. doi: 10.6023/cjoc202003049 shu

Nano Cu-CuFe₂O₄-Catalyzed Selective Reduction of α, β, γ, δ-Unsaturated Carbonyls in Alcohol Medium

Cong Yikang ,
Zeng Xianghua ^,

College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001

Corresponding author: Zeng Xianghua, xianghuazeng@zjxu.edu.cn
Received Date: 20 March 2020
Revised Date: 11 May 2020
Available Online: 27 May 2020
Fund Project: National Natural Science Foundation of Zhejiang Province LY17B030011Project supported by the National Natural Science Foundation of Zhejiang Province (No. LY17B030011)

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An efficient Cu-CuFe₂O₄ nanoparticle-catalyzed protodeboronation strategy has been developed for the chemoselective 1, 4-reduction of α, β, γ, δ-unsaturated ketones, carboxylic ester and cyano-ester. This protocol has the advantageous of the use of alcohol as hydrogen source and solvent, low catalyst loading (0.5 mol%), and excellent catalyst recyclability. Additionally, the Cu-CuFe₂O₄ catalyst has shown excellent performance in gram-scale reactions. Furthermore, the catalytic mechanism has also been discussed. The reactivity of (E)-γ, δ-unsaturated carbonyl products, an important class of γ, δ-unsaturated alkenes, enables easy access to 3-buten-1-ols, 3-buten-1-amines, γ-keto acids, cyclic ethers, and cyclic nitrones.
- α, β, γ, δ-unsaturated carbonyls,
- nano Cu-CuFe₂O₄,
- chemoselective,
- 1, 4-reduction
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Nano Cu-CuFe2O4-Catalyzed Selective Reduction of α, β, γ, δ-Unsaturated Carbonyls in Alcohol Medium

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通讯作者: 陈斌, bchen63@163.com

Nano Cu-CuFe₂O₄-Catalyzed Selective Reduction of α, β, γ, δ-Unsaturated Carbonyls in Alcohol Medium