Citation: Tao Pingfang, Huang Jun, Liu Yuzhao, Wei Guangming, Wang Yifei, Wei Xiansheng, Huang Guobao, Li Xiuying. Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts[J]. Chinese Journal of Organic Chemistry, ;2020, 40(6): 1630-1637. doi: 10.6023/cjoc201912030 shu

Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts

Tao Pingfang ^a,† ,
Huang Jun ^a,b,† ,
Liu Yuzhao ^a ,
Wei Guangming ^a ,
Wang Yifei ^a ,
Wei Xiansheng ^a ,
Huang Guobao ^a,, ,
Li Xiuying ^a,,

a.
Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, College of Chemistry and Food Science, Yulin Normal University, Yulin, Guangxi 537000
b.
College of Chemistry and Materials, Nanning Normal University, Nanning 530001

Corresponding author: Huang Guobao, lzjx0915@163.com Li Xiuying, lxya8401@163.com

^†

Received Date: 22 December 2019
Revised Date: 11 March 2020
Available Online: 31 March 2020
Fund Project: the Open Fund of Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology Research Grant KF04Project supported by the National Natural Science Foundation of China (No. 21961042), the Natural Science Foundation of Guangxi Province (No. 2018GXNSFAA294064) and the Open Fund of Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology Research Grant (No. KF04)the National Natural Science Foundation of China 21961042the Natural Science Foundation of Guangxi Province 2018GXNSFAA294064

Figures(2)

A new, versatile and highly efficient palladium-catalyzed asymmetric ring-opening reaction of oxabenzonor-bornadienes with a wide range of potassium trifluoroborate salts was developed. The corresponding cis-2-aryl-1, 2-dihydronaphthalen-1-ol products were obtained in good yields with moderate to good enantioselectivities under mild conditions.
- oxabenzonorbornadiene,
- trifluoroborate salt,
- asymmetric ring-opening reaction
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