Citation: Hu Yongqin, Huang Danfeng, Wang Kehu, Zhao Zhuanxia, Zhao Fangxia, Xu Weigang, Hu Yulai. Study on Allylation Reactions of Trifluoromethylated Acylhydrazones with Allylsilanes or Allylboronates[J]. Chinese Journal of Organic Chemistry, ;2020, 40(6): 1689-1696. doi: 10.6023/cjoc201912006 shu

Study on Allylation Reactions of Trifluoromethylated Acylhydrazones with Allylsilanes or Allylboronates

College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Huang Danfeng, huangdf@nwnu.edu.cn Hu Yulai, huyl@nwnu.edu.cn
Received Date: 4 December 2019
Revised Date: 17 February 2020
Available Online: 29 February 2020
Fund Project: the National Natural Science Foundation of China 21662030Project supported by the National Natural Science Foundation of China (No. 21662030)

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Allylation reactions of trifluoromethylated acylhydrazones with allyltrimethylsilane or pinacolyl allylboronate were found to proceed smoothly in the presence of Lewis acid to afford a series of trifluoromethylated homoallylic N-acylhydrazines with high yields. The results showed that the activity of pinacolyl allylboronate was higher than that of allyltrimethylsilane in allylation of trifluoromethylated acylhydrazones.
- trifluoromethylated acylhydrazone,
- allyltrimethylsilane,
- pinacolyl allylboronate,
- allylation,
- trifluoromethylated homoallylic N-acylhydrazine
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