Citation: Fang Xiaolong, Zhang Min, Duan Ning, Wang Xin, Zhu Hongping. Synthesis and Catalytic Property of New Aminophosphino Ruthenium Carbonyl Complexes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(1): 226-231. doi: 10.6023/cjoc201906022 shu

Synthesis and Catalytic Property of New Aminophosphino Ruthenium Carbonyl Complexes

Fang Xiaolong ^a,b ,
Zhang Min ^a ,
Duan Ning ^a ,
Wang Xin ^a,, ,
Zhu Hongping ^b,,

a.
Key Laboratory of Micro-nano Powder and Advanced Energy Materials of Anhui Higher Education Institutes, College of Chemistry and Materials Engineering, Chizhou University, Chizhou, Anhui 247000
b.
State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005

Corresponding author: Wang Xin, wangxin164@sina.com Zhu Hongping, hpzhu@xmu.edu.cn
Received Date: 18 June 2019
Revised Date: 22 August 2019
Available Online: 13 January 2019
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21802010, 21673191), the Natural Science Foundation of Anhui Province (No. 1808085QB48) and the Starting Grants for Young Teachers of Chizhou University (No. 2018YJRC001)the Natural Science Foundation of Anhui Province 1808085QB48the National Natural Science Foundation of China 21802010the National Natural Science Foundation of China 21673191the Starting Grants for Young Teachers of Chizhou University 2018YJRC001

Figures(3)

New carbonyl ruthenium complexes (μ-o-PPh₂C₆H₄NH)Ru₃(μ-H)(CO)₉ (2), (o-PPh₂C₆H₄NH)₂Ru(CO)₂ (3) and (μ-o-PPh₂C₆H₄NMe₂)₂Ru(CO)₃ (4) have been successfully synthesized by using ruthenium carbonyl and o-PPh₂C₆H₄NR₂ (R=H, Me) ligand. The three complexes have all been characterized by NMR and IR spectroscopies, elemental analysis and X-ray crystallography. Complexes 2 and 4 could catalyze the hydrogenation of benzaldehyde into benzyl alcohol. However, complex 3 showed no activity. This study reveals a correlation between structure and catalytic property, where the possible deactivation mode for the hydrogenation reaction using the aminophosphino ruthenium catalyst is discussed in view of the experimental work.
- aminophosphino ruthenium carbonyl,
- synthesis and characterization,
- catalytic hydrogenation,
- structure and property,
- deactivation
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