Citation: Sun Guijiu, Xiao Fanhua, Duan Weiliang. Palladium-Catalyzed Asymmetric 1, 4-Addition of Diarylphosphines to Quinone Monoketals[J]. Chinese Journal of Organic Chemistry, ;2020, 40(1): 61-68. doi: 10.6023/cjoc201905022 shu

Palladium-Catalyzed Asymmetric 1, 4-Addition of Diarylphosphines to Quinone Monoketals

a.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418
b.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Corresponding author: Xiao Fanhua, fhxiao@sit.edu.cn Duan Weiliang, duanwl@yzu.edu.cn
Received Date: 11 May 2019
Revised Date: 29 August 2019
Available Online: 13 January 2019
Fund Project: the National Natural Science Foundation of China 21472218Project supported by the National Natural Science Foundation of China (Nos. 21472218, 21672183)the National Natural Science Foundation of China 21672183

Figures(2)

An asymmetric 1, 4-addition reaction of diarylphosphines with quinone monoketals was studied. Pincer Pd complex was used as catalyst to generate a series of chiral phosphorus compounds with moderate to good enantioselectivities in high yields.
- palladium catalysis,
- diarylphosphine,
- 1symmetric addition
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