Citation: Chen Jinyang, Li Yuhan, Mei Lan, Wu Hongyu. Application of Photosensitizer 2, 4, 5, 6-Tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene in Photo-induced Transition-Metal-Free Organic Synthesis[J]. Chinese Journal of Organic Chemistry, ;2019, 39(11): 3040-3050. doi: 10.6023/cjoc201904022 shu

Application of Photosensitizer 2, 4, 5, 6-Tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene in Photo-induced Transition-Metal-Free Organic Synthesis

College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408000

Corresponding author: Chen Jinyang, chenjinyang@hnu.edu.cn
Received Date: 9 April 2019
Revised Date: 1 July 2019
Available Online: 24 November 2019
Fund Project: Project supported by the Basic and Frontier Research Project of Chongqing City (No. Cstc2018jcyjAX0051)the Basic and Frontier Research Project of Chongqing City Cstc2018jcyjAX0051

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Visible-light-promoted organic synthesis is an important research hotspot and frontier in organic chemistry in recent years. Particularly, as a novel organic photosensitizer, 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN) has showed excellent catalytic performance in visible-light-induced radical reactions. The recent progress on the transition-metal-free photosynthesis under visible-light catalyzed by 4CzIPN is reviewed, and the application of 4CzIPN for photocatalytic organic transformations from different precursors (including silicon reagent, carboxylic acid and its derivatives, sulfur-containing reagent and fluorine reagent) is included.
- 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN),
- organophotocatalyst,
- visible-light-induced,
- metal-free
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