Citation: Cheng Biao, Lu Peng, Zhao Jiajin, Lu Zhan. Cobalt-Catalyzed Dehydrogenative Silylation of Vinylarenes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1704-1710. doi: 10.6023/cjoc201903018 shu

Cobalt-Catalyzed Dehydrogenative Silylation of Vinylarenes

Department of Chemistry, Zhejiang University, Hangzhou 310058

Corresponding author: Lu Zhan, luzhan@zju.edu.cn
Received Date: 10 March 2019
Revised Date: 3 April 2019
Available Online: 16 June 2019
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21772171), the National Basic Research Program of China (973 Program, No. 2015CB856600), the Zhejiang Provincial Natural Science Foundation (No. LR19B020001), the K. P. Chao's High Technology Development Foundation of Zhejiang University and the Fundamental Research Funds for the Central Universitiesthe National Natural Science Foundation of China 21772171the National Basic Research Program of China 2015CB856600the Zhejiang Provincial Natural Science Foundation LR19B020001

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A highly chemo-, regio-, and stereo-selective cobalt-catalyzed dehydrogenative silylation of vinylarenes was described. The imidazoline iminopyridine cobalt complex could promote this reaction effectively and improve the chemoselectivity dramatically. This protocol used earth-abundant transition metal, readily available alkenes and hydrosilanes to construct valuable vinylsilanes. The reaction could be carried out in gramscale and the proposed mechanism was also described.
- cobalt-catalyzed,
- dehydrogenative silylation,
- alkenes,
- vinylsilanes,
- regio-and stereo-selectivity
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