Citation: Zhang Ting, Qiu Ziye, Cheng Xiaojie, Zhang Yulu, Wang Xuchun. Synthesis and Electroluminescence of Thiazolo[5, 4-b]carbazole Based Blue Fluorescent Materials[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2534-2540. doi: 10.6023/cjoc201902035 shu

Synthesis and Electroluminescence of Thiazolo[5, 4-b]carbazole Based Blue Fluorescent Materials

Zhang Ting ^a,, ,
Qiu Ziye ^a ,
Cheng Xiaojie ^a ,
Zhang Yulu ^a ,
Wang Xuchun ^a,b

a.
School of Chemistry and Material Engineering, Anhui Science and Technology University, Fengyang, Anhui 233100
b.
Engineering Research Center of Nano-Geo Materials of Ministry of Education, China University of Geosciences, Wuhan 430074

Corresponding author: Zhang Ting, tingzhang84@163.com
Received Date: 28 February 2019
Revised Date: 23 April 2019
Available Online: 15 September 2019
Fund Project: the Key Discipline of Anhui Science and Technology University AKZDXK2015A01the Key Research Funds of Anhui Province 1508085QB41the Open Project for Engineering Research Center of Nano-Geo Materials of Ministry of Education NGM2018KF006the Student's Platform for Innovation and Entrepreneurship Training Program of Anhui Science and Technology University 201810879X017Project supported by the Key Research Funds of Anhui Province (Nos. KJ2018A0525, 1508085QB41), the Student's Platform for Innovation and Entrepreneurship Training Program of Anhui Science and Technology University (No. 201810879X017), the Open Project for Engineering Research Center of Nano-Geo Materials of Ministry of Education (No. NGM2018KF006), and the Key Discipline of Anhui Science and Technology University (No. AKZDXK2015A01)the Key Research Funds of Anhui Province KJ2018A0525

Figures(7)

Two thiazolo[5, 4-b]carbazole based blue fluorescent materials, namely TCz-PCz and TCz-TPA, were synthesized by palladium catalyzed C-C and C-N coupling reactions, and their structures were confirmed by ¹H NMR, ¹³C NMR, mass spectrometry and elemental analysis. The thermal, photophysical, and electrochemical properties of these materials were fully investigated. The results indicate that these compounds possess thermal and amorphous stabilities with decomposition temperature up to 400℃ and glass transition temperatures of 119℃. Both TCz-PCz and TCz-TPA show strong blue emission in solution with high fluorescent quantum yields of 71% and 73%, respectively. These molecules show high HOMO energy levels of -5.41 and -5.21 eV that are favorable for hole injection and transportation from hole-transporting layer to the emitting layer in devices. The non-doped blue OLED using TCz-PCz as emitter through vacuum evaporation was fabricated for purpose of investigating its electroluminescence properties. The device exhibited stable blue electroluminescence, a low turn-on voltage of 3.1 V, a maximum luminance of 2190 cd·m^-2, and a maximum current efficiency of 2.88 cd·A^-1 were achieved, respectively.
- organic light-emitting diodes,
- blue fluorescent materials,
- thiazolo[5, 4-b]carbazole,
- non-doped,
- palladium catalyzed reaction
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