Citation: Zhou Xinyun, Xie Lingchao, Wu Kaile, Tan Songting. Synthesis and Photovoltaic Properties of Organic Dyes Containing Dendritic and 3D Triphenylamine Derivatives[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2589-2598. doi: 10.6023/cjoc201902023 shu

Synthesis and Photovoltaic Properties of Organic Dyes Containing Dendritic and 3D Triphenylamine Derivatives

Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105

Corresponding author: Tan Songting, tanst2008@163.com

^†

Received Date: 21 February 2019
Revised Date: 14 April 2019
Available Online: 19 September 2019
Fund Project: the National Natural Science Foundation of China 21875204Project supported by the National Natural Science Foundation of China (Nos. 21875204, 51173154)the National Natural Science Foundation of China 51173154

Figures(10)

Three organic dyes with dendritic and 3D triphenylamine derivatives as the donor unit, benzoic acid as the acceptor unit and benzothiadiazole (BT) or difluorobenzothiadiazole (DFBT) as the second acceptor were designed and synthesized. The influences of different donors and second acceptors on the photophysical, electrochemical and photovoltaic properties of dye-sensitizers were systematically investigated. The organic dye with dendritic triphenylamine derivative as a donor unit possesses a higher molar absorption coefficient, and the organic dye with 3D triphenylamine derivative (IDTTPA) as a donor unit has a broader absorption spectrum. The dye-sensitized solar cells based on three organic dyes achieved power conversion efficiencies of 5.27%, 4.22% and 5.50%, respectively. After optimizing the battery with 1 mmol·L^-1 co-adsorbent chenodeoxycholic acid (CDCA), the power conversion efficiencies of the organic dyes were increased to 5.46%, 4.98% and 6.26%, respectively.
- triphenylamine,
- benzothiadiazole,
- organic dye,
- photovoltaic property
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