Citation: Du Shanshan, Chai Zhengqi, Hu Jingyuan, Zhang Wen-Xiong, Xi Zhenfeng. Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P₆^4- Ligand[J]. Chinese Journal of Organic Chemistry, ;2019, 39(8): 2338-2342. doi: 10.6023/cjoc201902016 shu

Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P₆^4- Ligand

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Corresponding author: Zhang Wen-Xiong, wx_zhang@pku.edu.cn
Received Date: 18 February 2019
Revised Date: 25 March 2019
Available Online: 2 August 2019
Fund Project: the National Natural Science Foundation of China 21725201the National Natural Science Foundation of China 21572005Project supported by the National Natural Science Foundation of China (Nos. 21725201, 21890721, 21572005)the National Natural Science Foundation of China 21890721

Figures(5)

Direct synthesis of organophosphorus compounds from white phosphorus (P₄) is of great significance because this process avoids the industry pollution synthetic methods and provides the possibilities for many novel phosphorus-containing compounds. A trinuclear rare-earth metal complex[{(η⁵-C₅Me₅)LuCl}₃(THF)P₆] [Li(THF)₄] from lutetacyclopentadiene mediated P₄ functionalization was isolated and characterized. This novel complex contains a bicyclo[3.1.0]-P₆^4- ligand which is an unreported type. X-ray diffraction analysis shows that the bicyclo[3.1.0]-P₆^4- ligand adopts a boat-like conformation. Three lutetium atoms coordinate to this ligand in η¹, η³, η³ mode, respectively, and a novel[P₆Lu₃] cage has been formed. Density functional theory (DFT) calculations indicate that there are two three-center two-electron bonds.
- polyphosphorus ligand,
- white phosphorus activation,
- rare-earth-metal complex
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Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand

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Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P₆^4- Ligand