Citation: Diao Lu, Wang Renjie, Wang Niansheng, Liu Gang, Pu Shouzhi. A New Diarylethene Probe for Colorimetric Detection of CN^- and Fluorescent Recognition of Zn²⁺/H₂PO₄^-[J]. Chinese Journal of Organic Chemistry, ;2019, 39(7): 1930-1938. doi: 10.6023/cjoc201901038 shu

A New Diarylethene Probe for Colorimetric Detection of CN^- and Fluorescent Recognition of Zn²⁺/H₂PO₄^-

Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013

Corresponding author: Wang Renjie, bio-wrj@163.com Pu Shouzhi, pushouzhi@tsinghua.org.cn
Received Date: 24 January 2019
Revised Date: 22 March 2019
Available Online: 9 July 2019
Fund Project: the Project of the Science Funds of Jiangxi Education Office GJJ180614the Natural Science Foundation of Jiangxi Province 2017ACB20025Project supported by the National Natural Science Foundation of China (No. 41867053), and the Natural Science Foundation of Jiangxi Province (No. 20171ACB20025), the "5511" Science and Technology Innovation Talent Project of Jiangxi Province (No. 20165BCB18015), and the Project of the Science Funds of Jiangxi Education Office (No. GJJ180614)the "5511" Science and Technology Innovation Talent Project of Jiangxi Province 20165BCB18015the National Natural Science Foundation of China 41867053

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A new diarylethene 1-(3, 5-dimethylisoxazole-4-yl)-2-(2-methyl-5-[(3-aminonaphthol-2-yl)phenol-yl]-thiophene-3-yl)perfluorocyclopentene (1O) dual-response chemosensor has been synthesized, and its photochromic and fluorescent switch behaviors were systematically investigated by stimulation of lights and ions. The results indicated that 1O could serve as a CN^-/F^- "naked-eyes" colorimetric sensor with the color change from colorless to yellow, and act as a "Turn-on" fluorescence probe for specific detecting Zn²⁺. Moreover, the limits of detection of CN^- and Zn²⁺ were determined to be 1.03×10^-6 and 2.98×10^-8 mol·L^-1, respectively.
- diarylethene,
- chemosensor,
- Zn²⁺,
- CN^-,
- fluorescence enhancement
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沈阳化工大学材料科学与工程学院沈阳 110142

A New Diarylethene Probe for Colorimetric Detection of CN- and Fluorescent Recognition of Zn2+/H2PO4-

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通讯作者: 陈斌, bchen63@163.com

A New Diarylethene Probe for Colorimetric Detection of CN^- and Fluorescent Recognition of Zn²⁺/H₂PO₄^-