Citation: Zhou Guangwei, Zhang Lizhu, Xue Yahan, Li Jiarong. Progress of N-Benzyl Removal[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2428-2442. doi: 10.6023/cjoc201901031 shu

Progress of N-Benzyl Removal

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081

Corresponding author: Li Jiarong, jrli@bit.edu.cn
Received Date: 21 January 2019
Revised Date: 13 March 2019
Available Online: 16 September 2019
Fund Project: Project supported by the 086 Special Fund

Figures(16)

N-Benzyl is a common protecting group for organic amines, owing to its convenient and efficient removal. It plays an important role in organic synthesis, especially in the research of drugs and natural products. In recent years, a large number of researchers have conducted extensive studies on N-benzyl deprotection, but the related work is scattered and lacks systematic review. Therefore, the progress of N-benzyl removal is systematically and comprehensively summarized from the aspects of reductive, oxidative and acid-base debenzylation.
- organic amine,
- N-benzyl protection,
- reductive debenzylation,
- oxidative debenzylation,
- acid-base debenzylation
1. [1]
  Rong, G.-B. Protective Groups in Organic Synthesis, East China University of Science and Technology Press, Shanghai, 2004, pp.494~654(in Chinese).
2. [2]
  Huang, P.-Q.; Jin, L.-R.; Chen, A.-Q. Organic Synthesis, Higher Education Press, Beijing, 2006, pp.385~389(in Chinese).
3. [3]
  Wu, Y.-L.; Yao, Z.-J.; Hu, T.-S. Modern Organic Synthetic Chemistry, Science Press, Beijing, 2006, pp.27~73(in Chinese).
4. [4]
  Wu, Q.-P.; Li, S.-M. Protective Chemistry, Chemical Industry Press, Beijing, 2007, pp.239~277(in Chinese).
5. [5]
  Mackie, R.K.; Smith, D.M.; Aitken, R.A.; Meng, G. Guidebook to Organic Synthesis, Chemical Industry Press, Beijing, 2009, pp.210~223(in Chinese).
6. [6]
  Dong, Y.-S.; Dai, S.-A.; Pan, Z.-F.; Chen, J.-L. Ind.Catal. 2011, 19, 4(in Chinese). doi: 10.3969/j.issn.1008-1143.2011.04.002
7. [7]
  Bayat, Y.; Ebrahimi, H.; Fotouhi, F.F. Org. Process Res. Dev.2012, 16, 1733. doi: 10.1021/op300162d
8. [8]
  Jia, H.-P.; Ou, Y.-X.; Chen, B.-R.; Xu, Y.-J.; Chen, J.-T. Chin. J. Energ. Mater.1998, 6(4), 145(in Chinese).
9. [9]
  Qiu, W.-G.; Yu, Y.-Z. Chin.J.Synth.Chem. 1998, 6, 34(in Chinese).
10. [10]
  Davies, S.G.; Ichihara, O. Tetrahedron Lett.1999, 40, 9313. doi: 10.1016/S0040-4039(99)01954-1
11. [11]
  Couturier, M.; Andresen, B.M.; Jorgensen, J.B.; Tucker, J.L.; Busch, F.R.; Brenek, S.J.; Dube, P.; Ende, D.J.; Negri, J.T.P. Org. Process Res. Dev.2002, 6, 42. doi: 10.1021/op0102161
12. [12]
  Amat, M.; Llor, N.; Hidalgo, J.; Escolano, C.; Bosch, J. J. Org. Chem.2003, 68, 1919. doi: 10.1021/jo0266083
13. [13]
  Davies, S.G.; Nicholson, R.L.; Price, P.D.; Roberts, P.M.; Rueesell, E.D.; Savory, E.D.; Smith, A.D.; Thomson, J.E. Synlett 2004, 901.
14. [14]
  Srimurugan, S.; Murugan, K.; Chen, C. Chem. Pharm. Bull.2009, 57, 1421. doi: 10.1248/cpb.57.1421
15. [15]
  Davies, S.G.; Fletcher, A.M.; Hughes, D.G.; Lee, J.A.; Price, P.D.; Roberts, P.M.; Russell, A.J.; Smith, A.D.; Thomson, J.E.; Williams, O.M.H. Tetrahedron 2011, 67, 9975. doi: 10.1016/j.tet.2011.09.038
16. [16]
  Leitch, D.C.; Greene, T.F.; O'Keeffe, R.; Lovelace, T.C.; Powers, J.D.; Searle, A.D. Org. Process Res. Dev.2017, 21, 1806. doi: 10.1021/acs.oprd.7b00261
17. [17]
  Yoshida, K.; Nakajima, S.; Wakamatsu, T.; Ban, Y. Heterocycles 1988, 27, 1167. doi: 10.3987/COM-88-4525
18. [18]
  Gong, X.-B.; Sun, C.-H.; Pang, S.-P.; Zhang, J.; Li, Y.-C.; Zhao, X.-Q. Chin. J. Org. Chem.2012, 32, 486(in Chinese).
19. [19]
  Bellamy A.J. Tetrahedron 1995, 51, 4711.
20. [20]
  Wardle, R.B.; Edwards, W.W. WO 97/20785, 1997.
21. [21]
  Koskin, A.P.; Simakova, I.L.; Parmon, V.N. Russ. Chem. Bull.2007, 56, 2370. doi: 10.1007/s11172-007-0377-5
22. [22]
  Kalashnikov, A.I.; Sysolyatin, S.V.; Sakovich, G.V.; Surmacheva, I.A.; Surmachev, V.N.; Lapinab, Y.T. Russ. Chem. Bull.2009, 58, 2164. doi: 10.1007/s11172-009-0295-9
23. [23]
  Fotouhi-Far, F.; Bashiri, H.; Hamadanian, M. Propellants Explos., Pyrotech.2017, 42, 213. doi: 10.1002/prep.201600035
24. [24]
  Fotouhi-Far, F.; Bashiri, H.; Hamadanian, M.; Keshavarz, M.H. Inorg. Nano-Met. Chem.2017, 47, 1489. doi: 10.1080/24701556.2017.1357593
25. [25]
  Ji, H.-T.; Jing, Q.; Huang, J.-W.; Silverman, R.B. Tetrahedron 2012, 68, 1359. doi: 10.1016/j.tet.2011.12.013
26. [26]
  Zhu, S.-L.; Zhu, J.; Zhang, W.-P.; Cheng, C.; Shi, H.-J. Chin.J.Synth.Chem. 2014, 22, 664(in Chinese). doi: 10.3969/j.issn.1005-1511.2014.05.022
27. [27]
  Hou, T.-J.; Zhang, J.; Wang, C.-J.; Luo, J. Org. Chem. Front.2017, 4, 1819. doi: 10.1039/C7QO00357A
28. [28]
  Bailey, P.D.; Beard, M.A.; Dang, H.P.T.; Phillips, T.R.; Price, R.A.; Whittaker, J.H. Tetrahedron Lett.2008, 49, 2150. doi: 10.1016/j.tetlet.2008.01.104
29. [29]
  Cheng, C.-J.; Sun, J.-W.; Xing, L.-X.; Xu, J.-M.; Wang, X.-Y.; Hu, Y.-F. J. Org. Chem.2009, 74, 5671. doi: 10.1021/jo9007282
30. [30]
  Quast, H.; Walter, S.J.; Mueller, B. Heterocycles 2012, 85, 2449. doi: 10.3987/COM-12-12543
31. [31]
  Gao, J.-H. M.S.Thesis, Zhejiang University of Technology, Hangzhou, 2012(in Chinese).
32. [32]
  Zhang, M.-G.; Ma, Y.-Q.; Xia, Z.-J.; Chen, Z.-X. Chin. J. Pharm.2014, 45, 404(in Chinese).
33. [33]
  Lu, D.-Q.; Wang, W.-B.; Ling, X.-Q.; Xie, J.; Shen, D. Mod. Chem. Ind.2014, 34, 33(in Chinese). doi: 10.3969/j.issn.0253-4320.2014.02.008
34. [34]
  Yu, L.-D.; Xu, Q.-X.; Wang, X. J. Jiangxi Norm. Univ.(Nat. Sci. Ed.)2017, 45, 507(in Chinese).
35. [35]
  Désogère, P.; Rousselin, Y.; Poty, S.; Bernhard, C.; Goze, C.; Boschetti, F.; Denat, F. Eur. J. Org. Chem.2014, 35, 7831.
36. [36]
  Torres, E.; Leiva, R.; Gazzarrini, S.; Carrizo, M.R.; Vivas, M.F.; Moroni, A.; Naesens, L.; Vázquez, S. ACS Med. Chem. Lett.2014, 5, 831. doi: 10.1021/ml500108s
37. [37]
  Li, Y.; Manickam, G.; Ghoshal, A.; Subramaniam, P. Synth. Commun.2006, 36, 925. doi: 10.1080/00397910500466199
38. [38]
  Lou, D.-Y.; Wang, H.-S.; Liu, S.; Li, L.; Zhao, W.; Chen, X.-H.; Wang, J.-L.; Li, X.-Q.; Wu, P.-F.; Yang, J. Catal. Commun.2018, 109, 29.
39. [39]
  Shu, C.; Zheng, C.-Z.; Wang, R.-J.; Zhang, J.-Y. Chemistry 2004, 67(in Chinese).
40. [40]
  Elamin, B.; Anantharamaiah, G.M.; Royer, G.P.; Means, G.E. J. Org. Chem.1979, 44, 3442. doi: 10.1021/jo01333a048
41. [41]
  Ram, S.; Spicer, L.D. Tetrahedron Lett.1987, 28, 515. doi: 10.1016/S0040-4039(00)95769-1
42. [42]
  Anwer, M.K.; Spatola, A.F. Tetrahedron Lett.1981, 22, 4369. doi: 10.1016/S0040-4039(01)82959-2
43. [43]
  Anwer, M.K.; Spatola, A.F.; Bossinger, C.D.; Flanigan, E.; Liu, R.-C.; Olsen, D.B.; Stevenson, D. J. Org. Chem.1983, 48, 3503. doi: 10.1021/jo00168a025
44. [44]
  Adger, B.M.; O'Farrell, C.; Lewis, N.J.; Mitchell, M.B. Synthesis 1987, 53. doi: 10.1002/chin.198722132
45. [45]
  Khan, S.A.; Sivanandaiah, K.M. Synthesis 1978, 750. doi: 10.1055/s-1978-24877
46. [46]
  Felix, A.M.; Heimer, E.P.; Lambros, T.J.; Tzougraki, C.; Meienhofer, J. J. Org. Chem.1978, 43, 21, 4194.
47. [47]
  Gray, B.D.; Jeffs, P.W. J. Chem. Soc., Chem. Commun.1987, 18, 1329. doi: 10.1039/C39870001329
48. [48]
  Zheng, Y.; Wu, G.; Zhu, X.R.; Li, Y.-J.; Ma, Y.-H.; Zhao, X.; Lu, T.; Zhu, Y.-Q. Chem. Res. Chin.Univ. 2011, 27, 224.
49. [49]
  Chen, S.-P.; Liu, D.-Q.; Si, L.-L.; Chen, L.-G.; Yan, X.-L. Synth. Commun.2017, 47, 3, 238.
50. [50]
  Guo, M.-L.; Hong, K.-H.; Lv, Y.-F.; Ding, Y.; Li, C.-C.; Xu, H.; Qi, W.-X.; Chen, J.-Q.; Ji, M.; Cai, J. J. Chem. Res.2017, 2, 112.
51. [51]
  Bajwa, J.S.; Slade, J.; Repic, O. Tetrahedron Lett.2000, 41, 6025. doi: 10.1016/S0040-4039(00)01013-3
52. [52]
  Babu, S.N.N.; Srinivasa, G.R.; Santhosh, D.C.; Gowda, D.C. J. Chem. Res.2004, 66. doi: 10.3184/030823404323000846
53. [53]
  Babu, S.N.N.; Srinivasa, G.R.; Santhosh, D.C.; Gowda, D.C. Synth. Commun.2004, 34, 1831. doi: 10.1081/SCC-120034165
54. [54]
  Kim, S.S.; Lin, G.; Yang, J.W. Bull. Korean Chem. Soc.2004, 25, 249. doi: 10.5012/bkcs.2004.25.2.249
55. [55]
  Davies, S.G.; Mortimer, D.A.B.; Mulvaney, A.W.; Russell, A.J.; Skarphedinsson, H.; Smith, A.D.; Vickers, R.J. Org. Biomol. Chem.2008, 6, 1625. doi: 10.1039/b802204f
56. [56]
  Hungerhoff, B.; Samanta, S.S.; Roels, J.; Metz, P. Synlett 2000, 77. doi: 10.1002/chin.200017064
57. [57]
  Oikawa, Y.; Yoshioka, T.; Yonemitsu, O. Tetrahedron Lett.1982, 23, 885. doi: 10.1016/S0040-4039(00)86974-9
58. [58]
  Oikawa, Y.; Yoshioka, T.; Yonemitsu, O. Tetrahedron Lett.1982, 23, 889. doi: 10.1016/S0040-4039(00)86975-0
59. [59]
  Singh, S.B. Tetrahedron Lett.1995, 36, 2009. doi: 10.1016/0040-4039(95)00214-W
60. [60]
  Yamaura, M.; Suzuki, T.; Hashimoto, H.; Yoshimura, J.; Okamoto, T.; Shin, C.M. Bull. Chem. Soc. Jpn.1985, 58, 1413. doi: 10.1246/bcsj.58.1413
61. [61]
  Davies, S.G.; Ichihara, O. Tetrahedron Lett.1998, 39, 6045. doi: 10.1016/S0040-4039(98)01193-9
62. [62]
  Bull, S.D.; Davies, S.G.; Fenton, G.; Mulvaney, A.W.; Prasad, R.S.; Smith, A.D. Chem. Commun.2000, 337. doi: 10.1002/chin.200113073
63. [63]
  Bull, S.D.; Davies, S.G.; Fenton, G; Mulvaney, A.W.; Prasad, R.S.; Smith, A.D. J. Chem. Soc., Perkin Trans. 1 2000, 3765. doi: 10.1002/chin.200113073
64. [64]
  Chen, S.-S.; Qiu, W.-G.; Yu, Y.-Z. Chin.J.Explos.Propellants 2000, 2, 4(in Chinese).
65. [65]
  Qiu, W.-G.; Chen, S.-S; Yu, Y.-Z. Chin. J. Chem.1999, 17, 554.
66. [66]
  Gigg, R.; Conant, R. J. Chem. Soc. Chem. Commun.1983, 465.
67. [67]
  Haddach, A.A.; Kelleman, A.; Deaton-Rewolinski, M.V. Tetrahedron Lett.2002, 43, 399. doi: 10.1016/S0040-4039(01)02192-X
68. [68]
  Kong, W.; Fu, C.; Ma, S. Chem.-Eur. J.2011, 17, 13134. doi: 10.1002/chem.201102251
69. [69]
  Semak, V.; Escolano, C.; Arroniz, C. Tetrahedron:Asymmetry 2010, 21, 2542. doi: 10.1016/j.tetasy.2010.09.014
70. [70]
  Zhu, W.-T.; Gan, H.-F.; Chen, Z.-B.; Guo, K. Synth.Chem.2015, 23, 977(in Chinese). doi: 10.15952/j.cnki.cjsc.1005-1511.2015.10.0977
71. [71]
  Page, P.C.B.; Stephenson, G.R.; Harvey, J.; Slawin, A.M.Z. Synlett 2016, 27, 2500. doi: 10.1055/s-0035-1562603
72. [72]
  Zhao, F.; Tian, W.-H.; Luo, F.; Cheng, H.-L.; Jiang, Y.-B.; Chen, Z. Synth. Commun.2016, 46, 20, 1678.
73. [73]
  Feula, A.; Fossey, J.S. RSC Adv.2013, 3, 16, 5370. doi: 10.1039/C2RA22279E
74. [74]
  Kroutil, J.; Trnka, T.; Cerny, M. Org. Lett.2000, 2, 1681. doi: 10.1021/ol005746g
75. [75]
  Kroutil, J.; Trnka, T.; Cerny, M. Synthesis 2004, 446. doi: 10.1002/chin.199844207
76. [76]
  Moriyama, K.; Nakamura, Y.; Togo, H. Org. Lett.2014, 16, 3812. doi: 10.1021/ol501703y
77. [77]
  Ghosh, S.; Shashidhar, J. Tetrahedron Lett.2009, 50, 1177. doi: 10.1016/j.tetlet.2008.11.115
78. [78]
  Amat, M.; Pérez, M.; Minaglia, A.T.; Casamitjana, N.; Bosch, J. Org. Lett.2005, 7, 3653. doi: 10.1021/ol051242c
79. [79]
  Amat, M.; Escolano, C.; Gómez-Esqué, A.; Lozano, O.; Llor, N.; Griera, R.; Bosch, J. Tetrahedron:Asymmetry 2006, 17, 1581. doi: 10.1016/j.tetasy.2006.05.018
80. [80]
  Torregrosa, R.; Pastor, I.M.; Yus, M. Tetrahedron 2007, 63, 947. doi: 10.1016/j.tet.2006.11.032
81. [81]
  Morales, C.L.; Pagenkopf, B.L. Org. Lett.2008, 10, 157. doi: 10.1021/ol702376j
82. [82]
  Garst, M.E.; Dolby, L.J.; Esfandiari, S.; Fedoruk, N.A.; Chamberlain, N.C.; Avey, A.A. J. Org. Chem.2000, 65, 7098. doi: 10.1021/jo0008136
83. [83]
  Suzuki, H.; Tsukuda, A.; Kondo, M.; Aizawa, M.; Senoo, Y.; Nakajima, M.; Watanabe, T.; Yokoyama, Y.; Murakami, Y. Tetrahedron Lett.1995, 36, 1671. doi: 10.1016/0040-4039(95)00126-W
84. [84]
  Rao, T.S.; Pandey, P.S. Synth. Commun.2004, 34, 3121. doi: 10.1081/SCC-200028570
85. [85]
  Franceschini, N.; Da N.S.; Miel, H.; Sonnet, P. Heterocycl. Commun.2005, 11, 509.
86. [86]
  Franceschini, N.; Da N.S.; Miel, H.; Sonnet, P. Tetrahedron:Asymmetry 2003, 14, 3401. doi: 10.1016/j.tetasy.2003.09.010
87. [87]
  Nandi, P.; Dye, J.L.; Jackson, J.E. Tetrahedron Lett.2009, 50, 3864. doi: 10.1016/j.tetlet.2009.04.058
88. [88]
  Choudary, B.; Giles, R.G.; Jovic, F.; Lewis, N.; Moore, S.; Urquhart, M. Org. Process Res. Dev.2012, 16, 1927. doi: 10.1021/op300263w
89. [89]
  Shaw, A.Y.; Mclaren, J.A.; Nichol, G.S.; Hulme, C. Tetrahedron Lett.2012, 53, 2592. doi: 10.1016/j.tetlet.2012.03.033
90. [90]
  Lee, S.H.; Mu, Y.; Kim, G.W.; Kim, J.S.; Park, S.H.; Jin, T.; Lee, K.Y.; Ham, W.H. Heterocycles 2013, 87, 1749. doi: 10.3987/COM-13-12747
91. [91]
  Lam, T.Y.; Wang, Y.-P.; Danheiser, R.L. J. Org. Chem.2014, 45, 9396.
92. [92]
  Rombouts, F.; Franken, D.; Martinez-Lamenca, C.; Braeken, M.; Zavattaro, C.; Chen, J.S.; Trabanco, A.A. Tetrahedron Lett.2010, 51, 4815. doi: 10.1016/j.tetlet.2010.07.022
93. [93]
  Lima, H.M.; Sivappa, R.; Yousufuddin, M.; Lovely, C.J. J. Org. Chem.2014, 79, 2481. doi: 10.1021/jo4027337
94. [94]
  Chern, C.Y.; Huang, Y.P.; Kan, W.M. Tetrahedron Lett.2003, 44, 1039. doi: 10.1016/S0040-4039(02)02738-7
95. [95]
  Yu, Y.-Z.; Guan, X.-P. Chin. J. Energ. Mater.1999, 7, 1(in Chinese). doi: 10.3969/j.issn.1006-9941.1999.01.001
96. [96]
  Lv, L.-Y.; Ou, Y.-X.; Wang, J.-L.; Chen, B.-R. Fine Chem.2003, 20, 577(in Chinese). doi: 10.3321/j.issn:1003-5214.2003.10.001
97. [97]
  Bayat, Y.; Hajimirsadeghi, S.S.; Pourmortazavi, S.M. Org. Process Res. Dev.2011, 15, 810. doi: 10.1021/op200056j
98. [98]
  Bayat, Y.; Ebrahimi, H.; Fotouhi-Far, F. Org. Process Res. Dev.2012, 16, 1733. doi: 10.1021/op300162d
99. [99]
  Bayat, Y.; Hajighasemali, F. Propellants Explos. Pyrotech.2016, 41, 893. doi: 10.1002/prep.201500347
100. [100]
  Ou, Y.-X.; Liu, J.-Q. High Energy Density Compound, National Defence Industrial Press, Beijing, 2005, pp.96~110(in Chinese).
101. [101]
  Yang, B.W.; O'Rourke D, J.L.I. Synlett 1993, 195.
102. [102]
  See, Y.B. JP 321962, 1994.
103. [103]
  Wright, W.B.; Brabander, H.J. J. Org. Chem.1961, 26, 10 doi: 10.1021/jo01060a003
104. [104]
  Olofson, R.A.; Martz, J.T.Senet, J.P.; Piteau, M.; Malfroot, T. J. Org. Chem.1984, 49, 2081. doi: 10.1021/jo00185a072
105. [105]
  Kanth, J.V.B,; Reddy, C.K.; Periasamy, M. Synth. Commun.1994, 24, 313. doi: 10.1080/00397919408011190
106. [106]
  Igarashi, J.; Kobayashi, Y. Tetrahedron Lett.2005, 46, 6381. doi: 10.1016/j.tetlet.2005.06.171
107. [107]
  Annamalai, M.; Hristeva, S.; Bielska, M.; Ortega, R.; Kumar, K. Molecules 2017, 22, 827. doi: 10.3390/molecules22050827
108. [108]
  Pandey, G.; .Rani, K.S. Tetrahedron Lett.1988, 29, 4157. doi: 10.1016/S0040-4039(00)80443-8
109. [109]
  Smith, A.J.; Young, A.; Rohrbach, S.; O'Connor, E.F.; Allison, M.; Wang, H.-S.; Poole, D.L.; Tuttle, T.; Murphy, J.A. Angew. Chem., Int. Ed.2017, 56, 13747. doi: 10.1002/anie.201707914
110. [110]
  Golantsov, N.E.; Karchava, A.V.; Yurovskaya, M.A. Chem. Heterocycl. Compd. 2006, 42, 1021. doi: 10.1007/s10593-006-0198-8
111. [111]
  Montero, M.L.; Rodríguez, D.A.; Gotor, F.V.; Fernández, V.G.; Lavandera, I. Green Chem.2015, 46, 2794.
112. [112]
  Grayson, E, J.; Davis, B.G. Org. Lett.2005, 7, 2361. doi: 10.1021/ol050624f
113. [113]
  Baker, S.R.; Parsons A.F.; Wilson M. Tetrahedron Lett.1998, 39, 331. doi: 10.1016/S0040-4039(97)10480-4
114. [114]
  Yanada, R.; Obika, S.; Kobayashi Y.; Inokuma, T.; Oyama, M.; Yanada, K.; Takemoto Y. Adv. Synth. Catal.2005, 347, 1632. doi: 10.1002/adsc.200505147
1. [1]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
2. [2]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
3. [3]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
4. [4]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
5. [5]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
6. [6]
  Qi Wang , Yuqing Liu , Jiefei Wang , Yuan-Yuan Ma , Jing Du , Zhan-Gang Han . Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges. Acta Physico-Chimica Sinica, 2025, 41(10): 100120-0. doi: 10.1016/j.actphy.2025.100120
7. [7]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
8. [8]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
9. [9]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
10. [10]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
11. [11]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
12. [12]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
13. [13]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
14. [14]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
15. [15]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
16. [16]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
17. [17]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
18. [18]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
19. [19]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
20. [20]
  Fengxiao Wang , Zhiwei Miao , Yaofeng Yuan . 有机磷化学与化学教学. University Chemistry, 2025, 40(8): 158-168. doi: 10.12461/PKU.DXHX202410077

Get Citation

PDF

XML

Metrics

PDF Downloads(821)
Abstract views(14429)
HTML views(5888)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142