Citation: Qian Cunwei, Zhu Wenqian, Liu Junlong, Wang Xuemin, Qiu Ligan. Chitosan@Cu₂O as A Facile, Efficient and Reusable Catalyst for Ligand-Free C-O and C-N Coupling[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1695-1703. doi: 10.6023/cjoc201812003 shu

Chitosan@Cu₂O as A Facile, Efficient and Reusable Catalyst for Ligand-Free C-O and C-N Coupling

School of Chemical and Environmental Engineering, Yancheng Teachers College, Yancheng 224051

Corresponding author: Qian Cunwei, qiancunwei@163.com Qiu Ligan, chemistry_wmy@163.com
Received Date: 2 December 2018
Revised Date: 4 April 2019
Available Online: 16 June 2019
Fund Project: the Natural Science Foundation of the Jiangsu Higher Education Institutions of China 14JKD150009the Key Projects of Innovation and Entrepreneurship Training Program for College Students in Jiangsu Province 201710324003ZProject supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 14JKD150009) and the Key Projects of Innovation and Entrepreneurship Training Program for College Students in Jiangsu Province (No. 201710324003Z)

Figures(8)

The coupling reactions of phenols and nitrogen hetereocycles with aryl halide were catalyzed by a highly active, readily available and easily recoverable heterogeneous Cu catalyst which was prepared by simply stirring an suspension of chitosan in solvent with copper compound. The result showed that chitosan@Cu₂O catalyst catalyzed the coupling reactions of aryl halides with phenols and nitrogen hetereocycles to readily give the corresponding products in moderate to excellent yields. The highly active catalyst can be reused many times without losing its catalytic activity.
- chitosan@Cu catalyst,
- synthesize,
- catalyze,
- Cross-coupling
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通讯作者: 陈斌, bchen63@163.com

Chitosan@Cu₂O as A Facile, Efficient and Reusable Catalyst for Ligand-Free C-O and C-N Coupling