Citation: Shen Li, Zhang Jie, Xie Jianwei. Cu(Ⅱ)/Ag(Ⅰ)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides[J]. Chinese Journal of Organic Chemistry, ;2019, 39(4): 1153-1159. doi: 10.6023/cjoc201811010 shu

Cu(Ⅱ)/Ag(Ⅰ)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides

School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjian Bingtuan, Shihezi University, Shihezi 832003

Corresponding author: Xie Jianwei, cesxjw@foxmail.com
Received Date: 5 November 2018
Revised Date: 15 December 2018
Available Online: 28 April 2018
Fund Project: the National Natural Science Foundation of China 21868032the National Natural Science Foundation of China 21606153Project supported by the National Natural Science Foundation of China (Nos.21606153, 21868032)

Figures(1)

Cu(OTf)₂/AgOTf-catalyzed selective decarboxylation C-N crossing coupling of o-nitro aromatic carboxylic acids with o-aminobenzamides has been establised, affording seventeen diarylaminobenzamides in moderate yields. The present protocol provides a new choice for selective N-arylation of amines.
- decarboxylation,
- selective amination,
- o-nitro aromatic carboxylic acid,
- o-aminobenzamide
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