Citation: Tang Yucai, Ran Shutong, Wang Ping, Chen Piao. I₂O₅ Promoted Iodosulfonylation of Alkynes with Sulfonylhydrazides to Synthesis (E)-β-Iodovinyl Sulfones under Peroxide-Free Conditions[J]. Chinese Journal of Organic Chemistry, ;2019, 39(4): 1116-1121. doi: 10.6023/cjoc201810002 shu

I₂O₅ Promoted Iodosulfonylation of Alkynes with Sulfonylhydrazides to Synthesis (E)-β-Iodovinyl Sulfones under Peroxide-Free Conditions

Tang Yucai ^a,b,, ,
Ran Shutong ^a ,
Wang Ping ^a ,
Chen Piao ^a

a.
College of Chemistry and Materials Engineering, Hunan University of Arts and Science, Changde 415000
b.
Hunan Province Cooperative Innovation Center for the Construction & Development of Dongting Lake Ecologic Economic Zone, Changde 415000

Corresponding author: Tang Yucai, yctang1009@163.com
Received Date: 2 October 2018
Revised Date: 12 November 2018
Available Online: 7 April 2018
Fund Project: Project supported by the Start-up Foundation for Doctors of Hunan University of Arts and Science (No. 17BSQD32) and the Construct Program of the Key Discipline in Hunan Province (Applied Chemistry)the Start-up Foundation for Doctors of Hunan University of Arts and Science 17BSQD32

Figures(2)

A facile and efficient I₂O₅ promoted iodosulfonylation of alkynes for direct synthesis of (E)-β-iodovinyl sulfones is described. This procedure affords various synthetically useful β-iodosulfonyl alkenes in moderate to good yields under peroxide free conditions.
- I₂O₅,
- alkyne,
- sulfonylhydrazide,
- iodosulfonylation,
- (E)-β-iodovinyl
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沈阳化工大学材料科学与工程学院沈阳 110142

I2O5 Promoted Iodosulfonylation of Alkynes with Sulfonylhydrazides to Synthesis (E)-β-Iodovinyl Sulfones under Peroxide-Free Conditions

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通讯作者: 陈斌, bchen63@163.com

I₂O₅ Promoted Iodosulfonylation of Alkynes with Sulfonylhydrazides to Synthesis (E)-β-Iodovinyl Sulfones under Peroxide-Free Conditions