Citation: Zhang Shilong, Jiang Lasheng. Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 720-726. doi: 10.6023/cjoc201810001 shu

Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes

Zhang Shilong ,
Jiang Lasheng ^,

School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Corresponding author: Jiang Lasheng, 742923272@qq.com
Received Date: 1 October 2018
Revised Date: 29 October 2018
Available Online: 25 March 2018
Fund Project: the Key Project on the Integration of Industry, Education and Research of Guangdong Province 2012B090700003the National Natural Science Foundation of China 21072066the Foundation of Young Teachers of South China Normal University 14KJ02Project supported by the National Natural Science Foundation of China (No. 21072066), the Key Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2012B090700003), and the Foundation of Young Teachers of South China Normal University (No.14KJ02)

Figures(9)

Owing to the unique macrocyclic-cavity structure of crown ether and the capability of complexing with guest molecules, our group successfully designed and synthesized a novel Sailboat-Shaped self-complex by using intramolecular hydrogen bonds, which are able to switch its configuration during the different pH value. Furthermore, a novel catenane which based on the sailboat-shaped self-complex was obtained by using intermolecular charge transfer interaction and through the template-directed method, and its structure was identified by ¹H NMR, ¹³C NMR, HRMS and ¹H-¹H NOESY. It is hoped that it can be successfully controlled by the pH value conversion.
- self-complexes,
- charge transfer interaction,
- catenane
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