Citation: Song Yuwan, Feng Shaojing, Han Wei, Xiao Yaping. Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves[J]. Chinese Journal of Organic Chemistry, ;2019, 39(4): 1181-1186. doi: 10.6023/cjoc201808032 shu

Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves

School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023

Corresponding author: Han Wei, hanwei@njnu.edu.cn Xiao Yaping, xiaoyaping@njnu.edu.cn
Received Date: 28 August 2018
Revised Date: 13 November 2018
Available Online: 30 April 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21776139, 21302099), the Natural Science Foundation of Jiangsu Province (No. BK20161553), the Natural Science Foundation of Jiangsu Provincial Colleges and Universities (No. 16KJB150019)the Natural Science Foundation of Jiangsu Provincial Colleges and Universities 16KJB150019the National Natural Science Foundation of China 21776139the Natural Science Foundation of Jiangsu Province BK20161553the National Natural Science Foundation of China 21302099

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A convenient method for improving the conversion and selectivity of aniline to azoxybenzene by adjusting the ratio of silicon to titanium of TS-1 is reported. Over TS-1 (80), aryl anilines are transformed into the corresponding azoxybenzenes in good yields with H₂O₂ as the oxidant. The effect of different reaction parameters like molar ratio of H₂O₂ to aniline, solvent and the activity in catalyst recycling has been studied.
- anilines,
- oxidation,
- azoxybenzene,
- H₂O₂
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