Citation: Shen Tao, Ouyang Bo, Zhou Shaodong, Qian Chao, Chen Xinzhi. Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 873-877. doi: 10.6023/cjoc201808006 shu

Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium

Shen Tao ^a ,
Ouyang Bo ^a,b ,
Zhou Shaodong ^a ,
Qian Chao ^a,, ,
Chen Xinzhi ^a

a.
Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Zhejiang University, Hangzhou 310027
b.
Zhejiang Garden Biochemical High-Tech Co., LTD, Dongyang 322121

Corresponding author: Qian Chao, qianchao@zju.edu.cn
Received Date: 7 August 2018
Revised Date: 28 September 2018
Available Online: 26 March 2018
Fund Project: the National Key Research and Development Program of China 2016YFB0301800Project supported by the National Natural Science Foundation of China (No. 21476194) and the National Key Research and Development Program of China (No. 2016YFB0301800)the National Natural Science Foundation of China 21476194

Figures(3)

An efficient, solvent-free procedure using sodium as catalyst for the aminolysis of monoesters is reported. A detailed comparison of catalysts between sodium and sodium amide was made. It was found that the fresh sodium amide by in-situ synthesis of sodium with ammonia was more active than the indirectly adding sodium amide. As compared to the previously reported approaches, the procedure given in this work is much faster and performed under mild conditions. Furthermore, this procedure is applied successfully for the aminolysis of other monoesters.
- monoester,
- aminolysis,
- sodium,
- sodium amide
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