Citation: Ye Zhonghua, Yang Jiali, Ling Zhitian, Zhao Yi, Chen Guo, Zheng Yanqiong, Wei Bin, Shi Ying. Synthesis of Host Material Containing Indolocarbazole Group Featuring Bipolar and Thermally Activated Delayed Fluorecence and Its Application[J]. Chinese Journal of Organic Chemistry, ;2019, 39(2): 449-455. doi: 10.6023/cjoc201807006 shu

Synthesis of Host Material Containing Indolocarbazole Group Featuring Bipolar and Thermally Activated Delayed Fluorecence and Its Application

Ye Zhonghua ^a,† ,
Yang Jiali ^a,† ,
Ling Zhitian ^a ,
Zhao Yi ^a ,
Chen Guo ^b ,
Zheng Yanqiong ^b ,
Wei Bin ^b,, ,
Shi Ying ^a,,

a.
1School of Materials Science and Engineering, Shanghai University, Shanghai 200072
b.
Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072

Corresponding author: Wei Bin, bwei@shu.edu.cn Shi Ying, yshi@shu.edu.cn

^†

Received Date: 3 July 2018
Revised Date: 3 September 2018
Available Online: 26 February 2019
Fund Project: the National Key Basic Research and Development Program of China 2015CB655005the National Natural Science Foundation of China 61775130Project supported by the National Natural Science Foundation of China (Nos. 51725505 and 61775130), the National Key Basic Research and Development Program of China (973 program, No. 2015CB655005) and the Science and Technology Committee of Shanghai City (No. 15590500500)the National Natural Science Foundation of China 51725505the Science and Technology Committee of Shanghai City 15590500500the National Key Basic Research and Development Program of China 973 program

Figures(7)

The novel host material containing indolocarbazole group, 10-phenyl-10-(4-(7-phenylindolo[2, 3-b]carbazol-5(7H)-yl)phenyl)anthracen-9(10H)-one (DphAn-5PhIdCz), was designed and synthesized. The structures were characterized by NMR and their photophysical properties such as ultraviolet-visible absorption wavelength, fluorescence emission wavelength, fluorescence quantum yield, and transient fluorescence lifetime were measured. The DphAn-5PhIdCz was found to exhibit the characteritics of bipolar and thermally activated delayed fluorescence. By using this material as host of green emitter, (ppy)₂ Iracac, high-efficiency and low roll-off phosphorescent organic light-emitting diode (PhOLED) was fabricated with the maximum current efficiency of 56.12 cd·A^-1, the maximum external quantum efficiency of 15.70% and the maximum power efficiency of 71.3 lm·W^-1. These make DphAn-5PhIdCz a promising host for high performance PhOLED displays and lighting applications.
- indolocarbazole group,
- organic light-emitting diodes,
- host,
- bipolar,
- thermally activated delayed fluorescence
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