Citation: Zhao Qianyi, Liang Yuan, Xu Ting, Dou Ting, Zhang Jie, Chen Xuenian. Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane[J]. Chinese Journal of Organic Chemistry, ;2018, 38(12): 3286-3295. doi: 10.6023/cjoc201805050 shu

Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane

School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang 453007

Corresponding author: Zhao Qianyi, qyzhao@htu.edu.cn Chen Xuenian, xnchen@htu.edu.cn
Received Date: 28 May 2018
Revised Date: 10 July 2018
Available Online: 14 December 2018
Fund Project: the National Natural Science Foundation of China 21503070the National Natural Science Foundation of China 21501048the National Natural Science Foundation of China 21571052the Key Science and Technology Project of Henan Province 182102210377the National Natural Science Foundation of China 21771057Project supported by the National Natural Science Foundation of China (Nos. 21501048, 21503070, 21571052, 21771057) and the Key Science and Technology Project of Henan Province (No.182102210377)

Figures(7)

Reactions of OsCl₂(PPh₃)₃ (1) with bidentate nitrogen-based ligands at room temperature led to the formation of complexes OsCl₂(PPh₃)₂(diamine) (2~6) and OsCl₂(PPh₃)₂(Phen^*) (7~11). Complexes 2~11 showed high activity in the catalytic dehydrogenation of ammonia borane at 60℃, in THF/DME (V:V=1:1.6) solution with the catalyst loading of 5 mol%. Among all the catalysts, compound 4 demonstrated the highest catalytic activity, which represents the most efficient osmium catalyst in catalytic dehydrogenation of ammonia borane until now.
- osmium,
- complex,
- synthesis,
- catalytic dehydrogenation,
- ammonia borane
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