Citation: Chen Jinfa, Liu Xi, Han Bingbing, Ding Jindong, Zhang Youming, Lin Qi, Yao Hong, Wei Taibao. Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2741-2746. doi: 10.6023/cjoc201805003 shu

Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene

Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education; Key Laboratory of Polymer Materials of Gansu Province; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Wei Taibao, weitaibao@126.com
Received Date: 1 May 2018
Revised Date: 28 May 2018
Available Online: 15 October 2018
Fund Project: the National Natural Science Foundation of China 21661028the National Natural Science Foundation of China 21574104the National Natural Science Foundation of China 21662031the National Natural Science Foundation of China 21262032Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104, 21262032)

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Pillararenes, a new kind of macrocyclic aromatic compounds, are closely attracted because it was used to construct supramolecular gels. In this paper, an iodine-functionalized pillar[5]arene was designed and synthesized. This pillar[5]arene can form a stable supramolecular organogel in cyclohexanol, and phase transition temperature is approximately 96 ℃. The formation process of the organogel was characterized by concentration dependent ¹H NMR spectrum, 2D NOESY experiment, X-ray diffraction (XRD) powder diffraction and scanning electron microscope. The experiment results showed that a sheet-like structure was formed in self-assembly process of iodine-functionalized pillar[5]arene. Meanwhile, the fluorescent recognition properties of organogel were studied. With the addition of 0.5 equiv. of various metal ions (Fe³⁺, Ag⁺, Ca²⁺, Co²⁺, Ni²⁺, Cd²⁺, Pb²⁺, Zn²⁺, Cu²⁺, Mg²⁺ and Hg²⁺) onto the organogel, Hg²⁺ and Ag⁺ can cause blue fluorescence quenching of the organogel after 10 min. Therefore, this gel can be used for fluorescent detection of Hg²⁺ and Ag⁺.
- pillar [5]arene,
- supramolecular organogel,
- fluorescence detection,
- metal ion
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