Citation: Xu Fangning, Han Wei. Research Progress in Transition-Metal-Free Carbonylation Reactions[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2519-2533. doi: 10.6023/cjoc201804017 shu

Research Progress in Transition-Metal-Free Carbonylation Reactions

Xu Fangning ^a ,
Han Wei ^,

School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023

Corresponding author: Han Wei, hanwei@njnu.edu.cn
Received Date: 10 April 2018
Revised Date: 28 May 2018
Available Online: 7 October 2018
Fund Project: the National Natural Science Foundation of China 21776139the Natural Science Foundation of Jiangsu Provincial Colleges and Universities 16KJB150019Project supported by the National Natural Science Foundation of China (No. 21776139), the Natural Science Foundation of Jiangsu Province (No. BK20161553), the Natural Science Foundation of Jiangsu Provincial Colleges and Universities (No. 16KJB150019), the Qing Lan Project of Nanjing Normal University and the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Natural Science Foundation of Jiangsu Province BK20161553

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Carbon monoxide is a readily available and cheap C1 feedstock. Carbonylation, the direct incorporation of carbon monoxide into organic molecules, is a very important and fundamental chemical transformation. In recent years, developing transition-metal-free systems for the carbonylation has attracted highly attention from many researchers. The recent rearch progress of transition-metal-free carbonylations for the synthesis of aldehydes, ketones, esters, amides, acids, anhydrides, acyl chloride, and alcohols is reviewed. And the development and application prospects for transition-metal-free carbonylation are also discussed.
- carbon monoxide,
- carbonylation,
- transition-metal-free,
- synthetic methods
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