Citation: Wu Yaxing, Xi Yachao, Zhao Ming, Wang Siyi. Progress in Electrochemical C—H Functionalizations of Aromatic Compounds[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2590-2605. doi: 10.6023/cjoc201804001 shu

Progress in Electrochemical C—H Functionalizations of Aromatic Compounds

School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116

Corresponding author: Zhao Ming, ming815zhao@163.com
Received Date: 1 April 2018
Revised Date: 13 May 2018
Available Online: 5 October 2018
Fund Project: Project supported by the Fundamental Research Funds for the Central Universities (No. 2015XKMS048), the Natural Science Foundation of Jiangsu Province (No. BK20160254), and the National Natural Science Foundation of China (No. U1710102)

Figures(30)

Carbon-hydrogen bonds are the most extensive and basic chemical bonds existed in organic compounds. Electrochemical functionalization and direct conversion of aromatic C—H bonds is a green, sustainable, and atomically economical transformation pathway, which avoids the pre-functionalization of reactants. The anodic electrooxidation of aromatics allows the formation of C—X (X=C, N, O, S) bonds and the preparation of fused aromatic rings without the use of oxidants. Certain C—H activation reactions with chemoselectivity and regioselectivity can also be achieved by the optimization of electrode materials, electrolytes, and solvents. Vourious reactions focusing on the electrochemical functionalizations of C—H bonds in aromatic compounds are mainly reviewed.
- electrochemical synthesis,
- aromatics,
- C—H bond functionalization,
- fused aromatic compounds
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沈阳化工大学材料科学与工程学院沈阳 110142