Citation: Fang Lei, Lin Weibin, Shen Yun, Chen Chuanfeng. Applications of Helicenes and Their Derivatives in Asymmetric Catalysis[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 541-554. doi: 10.6023/cjoc201710028 shu

Applications of Helicenes and Their Derivatives in Asymmetric Catalysis

Fang Lei ^a,b ,
Lin Weibin ^a,b ,
Shen Yun ^a ,
Chen Chuanfeng ^a,b,,

a.
Key Laboratory of Molecular Recognition and Functions, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Chen Chuanfeng, cchen@iccas.ac.cn
Received Date: 24 October 2017
Revised Date: 16 November 2017
Available Online: 28 March 2017
Fund Project: the Strategic Priority Research Program of Chinese Academy of Sciences XDB12010400the National Natural Science Foundation of China 51373180the National Natural Science Foundation of China 21572233Project supported by the National Natural Science Foundation of China (Nos. 21572233, 51373180), and the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB12010400)

Figures(12)

Helicenes are a kind of π-conjugated helical compounds which are consisted of ortho-fused benzene or other aromatic rings. Compared to other kinds of chiral catalysts, studies on helicene-based catalysts with helical chirality showed late start and lagging development. However, since helicene molecules exhibit structural rigidity, thermal stability, easily functionalization, and excellent chiral environment for asymmetric catalysis by continuous elaborate curve in three-dimensional space, investigation on the synthesis of helicene-based chiral catalysts and their applications in asymmetric catalysis have attracted increasing interest in recent years. According to the different roles of the helicenes played in the asymmetric catalysis, the helicene-based catalysts can be classified into chiral inducers, helically chiral ligands and helical organocatalysts, and their applications in asymmetric catalysis will be focused on in this review, respectively.
- helicene,
- asymmetric catalysis,
- chiral induction,
- helical ligand,
- organocatalyst
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