Citation: Xu Huan, Zhang Maoyuan, Huang Xiang, Shi Dabin. Palladium Nanoparticles Supported on MIL-101 as an Efficient Heterogeneous Catalyst for Selective C₂ Arylation of Benzofuran[J]. Chinese Journal of Organic Chemistry, ;2018, 38(4): 832-839. doi: 10.6023/cjoc201710012 shu

Palladium Nanoparticles Supported on MIL-101 as an Efficient Heterogeneous Catalyst for Selective C₂ Arylation of Benzofuran

School of Pharmaceutical Sciences, Zunyi Medical College, Zunyi 563000

Corresponding author: Shi Dabin, sdb007.student@sina.com
Received Date: 10 October 2017
Revised Date: 5 December 2017
Available Online: 15 April 2017
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21362047), the Social Development Project of Guizhou Province (No. QKHSYZ-2013-3061) and the Science and Technology Foundation of Guizhou Province (No. QKHJZ-2014-2175)the Social Development Project of Guizhou Province QKHSYZ-2013-3061the Science and Technology Foundation of Guizhou Province QKHJZ-2014-2175the National Natural Science Foundation of China 21362047

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MIL-101 was synthesized by hydrothermal method, and Pd/MIL-101 catalyst was prepared by supporting palladium nanoparticles on metal-organic frameworks MIL-101. The microstructure and features of the catalyst were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), inductive coupled plasma (ICP), high resolution transmission electron microscopy (HRTEM) and N₂ adsorption, respectively. The experimental results reveal that the Pd nanoparticles on Pd/MIL-101 range from 1.5 nm to 2.5 nm, and the content of Pd nanoparticles is 1.5%. The catalytic experiments show that Pd/MIL-101 has a high catalytic activity for the C₂ arylation of benzofuran. For less active aryl bromides, the reaction gave moderate yields. Moreover, the catalyst could be recycled many times. After 5 runs of catalysis, the catalyst can still maintain high reactivity. This strategy provides a simple, effective method for the synthesis of benzofuran derivatives.
- metal-organic frameworks (MOFs),
- Pd nanoparticles,
- heterogeneous catalysis,
- C-H activation,
- benzofuran
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Palladium Nanoparticles Supported on MIL-101 as an Efficient Heterogeneous Catalyst for Selective C2 Arylation of Benzofuran

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Palladium Nanoparticles Supported on MIL-101 as an Efficient Heterogeneous Catalyst for Selective C₂ Arylation of Benzofuran