Citation: Wu Yan, Zhang Yang, Wu Jiajie, Zhou Jun, Liu Hong, Tu Tao. Visual Discrimination of Phosphate Anion via Selective Metallo-Hydrogel Formation[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 705-709. doi: 10.6023/cjoc201709048 shu

Visual Discrimination of Phosphate Anion via Selective Metallo-Hydrogel Formation

Wu Yan ^a ,
Zhang Yang ^b ,
Wu Jiajie ^b ,
Zhou Jun ^a ,
Liu Hong ^a ,
Tu Tao ^b,,

a.
Technical Guangxi Industrial Co., Ltd, Nanning 530001
b.
Department of Chemistry, Fudan University, Shanghai 200433

Corresponding author: Tu Tao, taotu@fudan.edu.cn
Received Date: 29 September 2017
Revised Date: 11 November 2017
Available Online: 21 March 2017
Fund Project: Project supported by the National Key R & D Program of China (No. 2016YFA0202902) and the National Natural Science Foundation of China (No. 21572036)the National Key R & D Program of China 2016YFA0202902the National Natural Science Foundation of China 21572036

Figures(4)

Due to high selective coordination ability of phosphate anion to the Zn center of pincer type terpyridine zinc nitrate complexes, intriguing visual recognition of phosphate anion via selective metallo-hydrogel formation has been successfully realized. Based on this interesting result, a series of control experiments were conducted including the study on thermodynamic stability, rheological property and microscopic morphology of the metallo-hydrogel, a plausible mechanism of the discrimination was proposed.
- metallo-hydrogel,
- visual recognition,
- phosphate anion,
- pincer type terpyridine zinc nitrate complex,
- selective
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