Citation: Gao Yuzhen, Tang Guo, Zhao Yufen. Recent Advances of Phosphorus-Centered Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 62-74. doi: 10.6023/cjoc201708023 shu

Recent Advances of Phosphorus-Centered Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds

Gao Yuzhen ^a,b ,
Tang Guo ^a ,
Zhao Yufen ^a,,

a.
Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
b.
Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Corresponding author: Zhao Yufen, yfzhao@xmu.edu.cn
Received Date: 11 August 2017
Revised Date: 31 August 2017
Available Online: 8 January 2017
Fund Project: the National Natural Science Foundation of China 21232005the National Postdoctoral Program for Innovative Talents BX201700244the National Basic Research Program of China 2013CB910700Project supported by the National Natural Science Foundation of China (Nos. 21232005, 21375113), the National Basic Research Program of China (No. 2013CB910700), the Fundamental Research Funds for the Central Universities (No. 20720160030), the National Postdoctoral Program for Innovative Talents (No. BX201700244)the Fundamental Research Funds for the Central Universities 20720160030the National Natural Science Foundation of China 21375113

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The scientists have been working on developing more efficient and green ways to synthesize organophosphorus compounds as they have broad utilities such as reagents for chemical reactions, photovoltaic materials, flame retardants, biologically active molecules and so on. The difunctionalization reactions between P-center radicals and unsaturated compounds provide powerful methods for the synthesis of organophosphorus compounds in least and concise steps. This review will summarize the recent development in this area on the basis of different types of P-centered radical initiators.
- phosphorus-centered radical,
- difunctionalization,
- unsaturated compounds
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