Citation: Lan Lixin, Xiao Jie, Xiao Huaiqiu, Yi Weiguo. Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds[J]. Chinese Journal of Organic Chemistry, ;2018, 38(2): 492-497. doi: 10.6023/cjoc201707029 shu

Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds

Hunan Chemical Vocational Technology College, Zhuzhou 412004

Corresponding author: Yi Weiguo, wgyi_hunan@126.com
Received Date: 25 July 2017
Revised Date: 16 October 2017
Available Online: 3 March 2017
Fund Project: the Scientific Research Fund of Hunan Provincial Education Department 15C0464Project supported by the Scientific Research Fund of Hunan Provincial Education Department (No. 15C0464)

Figures(1)

A facile and convenient ultrasonic-assisted method for the synthesis of 2-sulfonyl nitrogen heterocyclics has been developed. Using bromo-tris-pyrrolidino-phosphonium hexafluorophosphate (PyBroP) as catalyst, the reactions were carried out under ultrasound irradiation condition at room temperature for 1.0 h, and the 2-sulfonyl nitrogen heterocyclics were obtained in good yields with nitrogen heterocyclic N-oxides and sulfinic acid as raw materials. The reaction has the advantages of good substrate suitability, short reaction times and high yields, which provides a efficient approach for the synthesis of 2-sulfonyl nitrogen heterocyclics and their derivatives.
- 2-sulfonyl nitrogen heterocyclics,
- nitrogen heterocyclic N-oxides,
- sulfinic acids,
- ultrasound-assisted
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