Citation: Liu Rui, Zhong Xianghong, Liu Zhenyu, Liang Shengbiao, Zhu Hongping. Selective Ethylene Oligomerization Catalyzed by the Chromium Complex Bearing N-Tetrahydrofurfuryl PNP Ligand[J]. Chinese Journal of Organic Chemistry, ;2017, 37(9): 2315-2321. doi: 10.6023/cjoc201703010 shu

Selective Ethylene Oligomerization Catalyzed by the Chromium Complex Bearing N-Tetrahydrofurfuryl PNP Ligand

a.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005
b.
Maoming Branch R & D Institute, SINOPEC, Maoming 525011

Corresponding author: Zhong Xianghong, zhongxh.mmsh@sinopec.com Zhu Hongping, hpzhu@xmu.edu.cn
Received Date: 3 March 2017
Revised Date: 5 May 2017
Available Online: 17 September 2017
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21473142, 21673191) and the Innovative Research Team Program (No.IRT_14R31)National Natural Science Foundation of China 21673191Innovative Research Team Program IRT_14R31National Natural Science Foundation of China 21473142

Figures(5)

The N-tetrahydrofurfuryl diphoshinoamine (PNP) ligand (E) was synthesized by means of two-step salt elimination reactions where separation of the two kinds of the aminyl lithium salts for the respective reactions is necessary for obtaining a high yield of E. The ligand reacted with CrCl₃(THF)₃ and Cr(CO)₆ to give P, P-chelation complexes[{Ph₂PN(CH₂OC₄H₇)-PPh₂}CrCl₂(μ-Cl)]₂ (1) and[Ph₂PN(CH₂OC₄H₇)PPh₂]Cr(CO)₄ (2), respectively. Complexes E, 1 and 2 were characterized by spectroscopy and elemental analysis, of which complex 2 was further confirmed by X-ray crystallography. Upon activation with methylaluminoxane (MAO) or AlEt₃, the catalyst systems including 1, 2, E/CrCl₃(THF)₃, E/Cr(acac)₃ and E/CrCl₂(THF)₂ were investigated. The best catalytic activity was achieved by 15.9 kg (product)/g (Cr)·h in which a selectivity of 63.6% for 1-C₈ was obtained.
- chromium complexes,
- catalytic property,
- ethylene tri-/tetramerization,
- catalytic reaction conditions
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