Citation: Wang Tao, Xu Kai, Meng Tuanjie, Zhang An'an, Wang Hongyu, Shen Sisi, Liu Lantao. N-Heterocyclic Carbene-Palladium(Ⅱ) Complexes with Acridine Ligand:Synthesis, Characterization and Catalytic Applications[J]. Chinese Journal of Organic Chemistry, ;2017, 37(7): 1794-1799. doi: 10.6023/cjoc201701039 shu

N-Heterocyclic Carbene-Palladium(Ⅱ) Complexes with Acridine Ligand:Synthesis, Characterization and Catalytic Applications

School of Chemistry and Chemical Engineering, Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, Shangqiu Normal University, Shangqiu 476000

Corresponding author: Wang Tao, wt67751726@126.com Liu Lantao, liult05@iccas.ac.cn
Received Date: 19 January 2017
Revised Date: 2 March 2017
Available Online: 8 July 2017
Fund Project: Project supported by the National Natural Sciences Foundation of China (Nos. U1404205, 21572126 and 21202095), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT016) and the Key Scientific and Technological Project of Henan Province (No.152102410056)the National Natural Sciences Foundation of China U1404205the National Natural Sciences Foundation of China 21572126the Key Scientific and Technological Project of Henan Province 152102410056the Program for Science & Technology Innovation Talents in Universities of Henan Province 14HASTIT016the National Natural Sciences Foundation of China 21202095

Figures(2)

Two novel N-heterocyclic carbene-palladium(Ⅱ) complexes were conveniently synthesized through one-pot reactions of imidazolium salts, palladium chloride and acridine. The new complexes have been fully characterized by ¹H NMR, ¹³C NMR, elemental analysis, and X-ray single-crystal diffraction. Moreover, the obtained palladium(Ⅱ) complexes were the effective catalyst precursors for the Suzuki-Miyaura coupling of aryl as well as benzyl chlorides with arylboronic acids. Under the optimal conditions, all reactions proceeded successfully to give the desired products in good to almost quantitative yields.
- N-heterocyclic carbene,
- palladium,
- acridine,
- Suzuki-Miyaura cross-coupling
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