Citation: Peng Jun, Xing Yuxiu, Xu Kai. A Study on Synthesis of Janus Heterofunctional Cubic Silsesquioxanes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(3): 636-645. doi: 10.6023/cjoc201608032 shu

A Study on Synthesis of Janus Heterofunctional Cubic Silsesquioxanes

Peng Jun ^a,b,*,, ,
Xing Yuxiu ^a ,
Xu Kai ^a,*,,

a.
Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650
b.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Corresponding author: Peng Jun, pengjun3032@126.com Xu Kai, xk@gic.ac.cn
Received Date: 31 August 2016
Revised Date: 22 November 2016

Fund Project: the Guangzhou Science and Technology Plan Projects 201505051006333Project supported by the National Natural Science Foundation of China 21174162the Province Natural Science Fund of Guangdong Province 2016A030313162

Figures(13)

Design and synthesis of well-defined hetero-functional cubic silsesquioxane remain as international research focuses and challenges. In this work, we demonstrated in detail the synthesis of two Janus hetero-functional cubic silsesquioxane. We applied similar "bottom-up" method to construct the aimed Janus HFCSQ, which was carried out by using cyclic tetrasiloxanes as synthetic platforms and followed by further hydrolysis and cage-closure. The obtained products exhibited good solubility in THF, CHCl3 and DMSO, which embodied themselves potential use in further derivations and processing. The precise structure of these obtained Janus HFCSQ were fully characterized by FTIR, ¹H NMR, Maldi-tof MS, ²⁹Si NMR, WAXD and TGA. Red-shifts observed from Photoluminescence UV-vis analysis further confirmed extended conjugation of the silsesquioxane cages, which in turn proved the formation of completed cages.This work provided us a versatile novel method to prepare the resulting Janus HFCSQs, which can widely expand the species of silsesquioxane monomers and applications as well.
- hetero-functional cubic silsesquioxane,
- Janus nanoparticle,
- functional monomer
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