Citation: Liu Wei, Zheng Xinyu, Zeng Jianguo, Cheng Pi. Visible Light Promoted C-H Functionalization Reactions of Tertiary Amines[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 1-19. doi: 10.6023/cjoc201607040 shu

Visible Light Promoted C-H Functionalization Reactions of Tertiary Amines

Liu Wei ^a ,
Zheng Xinyu ^a ,
Zeng Jianguo ^a,b ,
Cheng Pi ^a,b,*,,

a.
National and Provincial Union Engineering Research Center for the Veterinary Herbal Medicine Resources and Initiative, College of Horticulture and Landscape Architecture, Hunan Agricultural University, Changsha 410128
b.
Hunan Co-innovation Center for Utilization of Botanicals Functional Ingredients, Hunan Agricultural University, Changsha 410128

Corresponding author: Cheng Pi, picheng55@126.com
Received Date: 27 July 2016
Revised Date: 1 September 2016

Fund Project: the National Natural Science Foundation of China 31402109

Figures(30)

The tertiary amine motif is an important structure component of multitudinous natural products and drug molecules.Visible light promoted C-H functionalization of tertiary amines has recently received much attention and facilitated the synthesis of alkaloids and drug molecules.Based on photoredox catalysis, visible light is able to induce the formation of iminium cations or α-amino carbon radicals through single electron transfer process which can participate in multitudinous type of organic reactions and complete C-H functionalization of tertiary amines.In this review, the research progress of photoredox catalytic C-H func-tionalization was categorized and summarized.
- tertiary amines,
- visible light,
- photoredox catalysis,
- C-H functionalization
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