Citation: An Yulong, Tan Hongru, Zhao Shengyin. Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds[J]. Chinese Journal of Organic Chemistry, ;2017, 37(1): 226-231. doi: 10.6023/cjoc201607007 shu

Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

College of Chemistry, Chemical and Biological Engineering, Donghua University, Shanghai 201620

Corresponding author: Zhao Shengyin, syzhao8@dhu.edu.cn
Received Date: 5 July 2016
Revised Date: 17 August 2016

Fund Project: the Fundamental Research Funds for the Central Universities from the Ministry of Education of China BCZD2016004the Fundamental Research Funds for the Central Universities from the Ministry of Education of China CUSF-DH-D-2016028the Natural Science Foundation of Shanghai Municipality 15ZR1401400

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Aromatic azo compounds are widely used as organic dyes, biological medicines, food additives, radical initiators and so on.This paper describes an efficient protocol for the synthesis of aromatic azo compounds from anilines via Ag₂CO₃ mediated oxidative dehydrogenative coupling reactions in the presence of (CH₃)₃COK in PhCl.The yields are up to 92%, and this method is easy-operation and provides a practical process to synthesize aromatic azo compounds under mild conditions.
- anilines,
- Ag₂CO₃,
- (CH₃)₃COK,
- aromatic azo compounds
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Ag2CO3 Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

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Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds