Citation: Li Ming, Ning Jiabin, Yu Le, Wen Lirong. Copper-Promoted Synthesis of Thiochromones Derivatives[J]. Chinese Journal of Organic Chemistry, ;2016, 36(11): 2715-2722. doi: 10.6023/cjoc201605032 shu

Copper-Promoted Synthesis of Thiochromones Derivatives

1.
State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042

Corresponding author: Wen Lirong, wenlirong@qust.edu.cn
Received Date: 17 May 2016
Revised Date: 12 June 2016

Fund Project: the National Natural Science Foundation of China 21372137the National Natural Science Foundation of China 21572110the Natural Science Foundation of Shandong Province ZR2014BM006

Figures(3)

A new methodology to high chemoselectively synthesize thiochromone derivatives from β-oxodithioesters and substituted o-bromoacetophenones promoted by CuI/1, 10-phen system based on the substrate-design concept has been developed. This approach has advantages of simple and efficient operation, and high yields.
- thiochromones,
- β-oxodithioesters,
- substituted o-bromoacetophenones,
- copper,
- Ullmann coupling reaction,
- synthesis
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