Citation: Zou Xiaochuan, Shi Kaiyun, Li Jun, Wang Yue, Wang Cun, Deng Chaofang, Ren Yanrong, Tan Jun, Fu Xiangkai. Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1765-1778. doi: 10.6023/cjoc201604010 shu

Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States

Zou Xiaochuan ^a,b ,
Shi Kaiyun ^a,*,, ,
Li Jun ^a ,
Wang Yue ^a ,
Wang Cun ^a ,
Deng Chaofang ^a ,
Ren Yanrong ^a ,
Tan Jun ^a ,
Fu Xiangkai ^b,*,,

a.
Department of Biological and Chemical Engineering, Chongqing University of Education, Nan'an 400067
b.
Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education, Research Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, Southwest University, Beibei 400715

Corresponding author: Shi Kaiyun, shiky@cque.edu.cn Fu Xiangkai, fxk@swu.edu.cn
Received Date: 5 April 2016
Revised Date: 3 May 2016

Fund Project: the Scientific and Technological Research Program of Chongqing Municipal Education Commission Nos. KJ1501411，KJ131513，KJ131512Projects supported by the Basic and Frontier Research Project of Chongqing Nos. cstc2015jcyjA0317，cstc2013jcyjA50033and the Innovative Research Team in Chongqing University of Education No. KYC-cxtd03-20141z02the Key Laboratory of Green Synthesis and Analysis of Chongqing University of Education No. 16xjpt08the Innovation Team Building at Institutions of Higher Education in Chongqing No. KJTD201325

Figures(8)

The epoxidation catalyzed by transition metals (Cr, Ni, Co, Ru, Mn) has been received widespread attention over the past decades, and the corresponding epoxides are widely used in the synthesis of pharmaceuticals, fine chemicals and pesticides. Compared to other transition metals, metal Mn catalyst has been widely used in organic synthesis due to its inexpensive, environment-friendly, chemical stability and high catalytic activity. This paper reviews the recent progress on epoxidation of olefins catalyzed by the catalysts which were formed by the reaction of different valence metal Mn(II, III, and V) and different N_XO_Y ligands in different oxidants/co-catalyst systems. At the same time, the Mn catalysts with different valence states are involved in the process of the epoxidation of olefins and the mechanism of how to transfer the oxygen of reactive intermediates to the olefins was discussed.
- metal manganese(II, III, V) catalysts,
- ligands,
- epoxidation,
- organic polymer/inorganic phosphate melt (Zr, Zn, Al, Ca),
- catalytic mechanism
1. [1]
2. [2]
  Limburg, B.; Bouwman, E.; Bonnet, S. Coord. Chem. Rev. 2012, 256, 1451.
3. [3]
  Talsi, E. P.; Bryliakov, K. P. Coord. Chem. Rev, 2012, 256, 1418.
4. [4]
  Monfared, H. H.; Ghorbanloo, M.; Aghapoor, V.; Mayer, P. Appl. Catal. A: Gen. 2010, 372, 209.
5. [5]
  Ballistreri, F. P.; Brinchi, L.; Germani, R.; Savelli, G.; Tomaselli, G. A.; Toscanoa, R. M. Tetrahedron 2008, 64, 10239.
6. [6]
  Wegermann, C. A.; Ribeiro, R. R.; Ucoski, G. M.; Nakagaki, S.; Nunes, F. S.; Drechsel1, S. M. Appl. Catal. A: Gen. 2014, 471, 56.
7. [7]
  Stamatis, A.; Vartzouma, C.; Louloudi, M. Catal. Commun. 2011, 12, 475.
8. [8]
  Bagherzadeh, M.; Latifi, R.; Tahsini, L. J. Mol. Catal. A: Chem. 2006, 260, 163.
9. [9]
  Amini, M.; Bagherzadeh, M. M.; Oradi, S. Z.; Boghaei, D. M.; Ellern, A.; Woo, L. K. J. Coord. Chem. 2013, 66, 464.
10. [10]
  Zhang, W.; Loebach, J. L.; Wilson, S. R.; Jacobsen, E. N. J Am Chem Soc. 1990, 112, 2801.
11. [11]
  Visser, S. P. D.; Sason, S. J. Am. Chem. Soc. 2003, 125, 7413.
12. [12]
  Xia, Q. H.; Ge, H. Q.; Ye, C. P.; Liu, Z. M.; Su, K. X. Chem. Rev. 2005, 105, 1603.
13. [13]
  Keerthi, K. K.; Thomas, A. M.; Sindhu, K. S.; Anilkumar, G. Tetrahedron 2016, 72, 1.
14. [14]
  Neu, H. M.; Baglia, R. A.; Goldberg, D. P. Acc. Chem. Res. 2015, 48, 2754.
15. [15]
  Chen, Z. Q.; Yin, G. C. Chem. Soc. Rev. 2015, 44, 1083.
16. [16]
  Chang, S.; Galvin, J. M.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 6937.
17. [17]
  Choudary, B. M.; Chowdari, N. S.; Kantam, M. L.; Santhi, P. L. Catal. Lett. 2001, 76, 213.
18. [18]
  Sutra, P.; Brunel, D. Chem Commun. 1996, 2485.
19. [19]
  Angelino, M. D.; Laibinis, P. E. Macromolecules 1998, 31, 7581.
20. [20]
  Leadbeater, N. E.; Marco, M. Chem. Rev. 2002, 102, 3217.
21. [21]
  Sui, Y.; Fu, X. K.; Zeng, R. Q.; Ma, X. B. J. Mol. Catal. A: Chem. 2004, 217, 133.
22. [22]
23. [23]
  Bai, R. F.; Fu, X. K.; Bao, H. B.; Ren, W. S. Catal. Commun. 2008, 9, 1588.
24. [24]
  Ren, W. S.; Fu, X. K.; Bao, H. B.; Bai, R. F.; Ding, P. P.; Sui, B. L. Catal. Commun. 2009, 10, 788.
25. [25]
  Ren, W. S.; Fu, X. K. J. Mol. Catal. A: Chem. 2009, 312, 4.
26. [26]
27. [27]
  Shen, H. S.; Fu, X. K.; Bao, H. B.; Chen, J. X., Gong, B.W. Polym. Adv. Technol. 2009, 20, 77.
28. [28]
  Zou, X. C.; Chen, S. C.; Ren, Y. R.; Shi, K.Y., Li, J., Fu, X. K. Sci. China. Chem. 2012, 55, 2396.
29. [29]
  Tu, X. B.; Fu, X. K.; Hu, X. Y.; Li, Y. D. Inorg. Chem. Commun. 2010, 13, 404.
30. [30]
31. [31]
  Gong, B. W.; Fu, X. K.; Chen, J. X.; Li, Y. D.; Zou, X. C.; Tu, X. B.; Ding, P. P.; Ma, L. P. J. Catal. 2009, 262, 9.
32. [32]
  Zou, X. C.; Fu, X. K.; Li, Y. D.; Tu, X. B.; Fu, S. D.; Luo, Y. F.; Wu, X. J. Adv. Synth. Catal. 2010, 352, 163.
33. [33]
34. [34]
35. [35]
  Zou, X. C.; Shi, K. Y.; Wang, C. Chin. J. Catal. 2014, 35, 1446.
36. [36]
  Huang, J.; Fu, X. K.; Wang, G.; Li, C,; Hu X. Y. Dalton Trans. 2011, 40, 3631.
37. [37]
  Huang, J.; Fu, X. K.; Miao, Q. Catal. Sci. Technol. 2011, 1, 1472.
38. [38]
  Huang, J.; Fu, X. K.; Wang, G.; Miao, Q.; Wang, G. M. Dalton Trans. 2012, 41, 10661.
39. [39]
  Cai, J. L.; Huang, J.; Li, C. M.; Feng, H.; Liu, Z. G. RSC Adv. 2013, 3, 18661.
40. [40]
  Jia, Z. Y.; Fu, X. K.; Luo, Y. F.; Zhang, H. Z.; Huang, X. M.; Wu, H. J. Inorg. Organomet. Polym. Mater. 2012, 22, 415.
41. [41]
  Huang, X. M.; Fu, X. K.; Jia, Z. Y.; Miao, Q.; Wang, G. M. Catal. Sci. Technol. 2013, 3, 415.
42. [42]
  Huang, J.; Tang, M.; Li, X.; Zhong, G. Z.; Li, C. M. Dalton Trans. 2014, 43, 17500.
43. [43]
  Huang, J.; Tang, M.; Li, C. M. RSC Adv. 2014, 4, 46498.
44. [44]
  Kam, P. H.; Wing, L. W.; Kin, M. L.; Cheuk, P. L.; Tak, H. C.; Kwok, Y. W. Chem. Eur. J. 2008, 14, 7988.
45. [45]
  Qi, B.; Lou, L. L.; Yu, K.; Bian, W.; Liu, S. X. Catal. Commun. 2011, 15, 52.
46. [46]
  Zheng, W. G.; Tan, R.; Zhao, L. L.; Chen, Y. J.; Xiong, C. W.; Yin, D. H. RSC Adv. 2014, 4, 11732.
47. [47]
  Qi, J. Y.; Li, Y. M.; Zhou, Z. Y.; Che, C. M.; Yeung, C. H.; Chan, A. S. C. Adv. Synth. Catal. 2005, 347, 45.
48. [48]
  Dong, J. J.; Saisaha, P.; Meinds. T, G.; Alsters, P. L.; Ijpeij, E. G.; Van Summeren, R. P.; Mao, B.; Fananas, M. M.; de Boer, J. W.; Hage, R.; Feringa, B. L.; Browne, W. R. ACS Catal. 2012, 2, 1087.
49. [49]
  Rich, J.; Manrique, E.; Molton, F.; Duboc, C.; Marie, N. C.; Rodriguez, M.; Romero, I. Eur. J. Inorg. Chem. 2014, 2663.
50. [50]
  Stamatis, A.; Vartzouma, C.; Louloudi, M. Catal. Commun. 2011, 12, 475.
51. [51]
  Murphy, A.; Dubois, G.; Stack, T. D. P. J. Am. Chem. Soc. 2003, 125, 5250.
52. [52]
  Murphy, A.; Pace, A; Stack, T. D. P. Org. Lett. 2004, 6, 3119.
53. [53]
  Wu, M.; Wang, B.; Wang, S.; Xia, C.; Sun, W. Org. Lett. 2009, 11, 3622.
54. [54]
  Maity, N. C.; Bera, P. K.; Ghosh, D.; Abdi, S. H. R.; Kureshy, R. I.; Khan, N. U. H.; Bajaj, H. C.; Suresh, E. Catal. Sci. Technol. 2014, 4, 208.
55. [55]
  Wang, X.; Miao, C.; Wang, S.; Xia, C.; Sun, W. ChemCatChem 2013, 5, 2489.
56. [56]
  Ottenbacher, R. V.; Bryliakov, K. P.; Talsi, E. P. Adv. Synth. Catal. 2011, 353, 885.
57. [57]
  Dai,W.; Li, J.; Li, G. S.; Yang, H.; Wang, L. Y.; Gao, S. Org. Lett. 2013, 15, 4138.
58. [58]
  Dai,W.; Shang, S. S.; Chen, B.; Li, G. S.; Wang, L. Y.; Ren, L. H.; Gao, S. J. Org. Chem. 2014, 79, 6688.
59. [59]
  Hashihayata, T.; Ito, Y.; Katsuki, T. Tetrahedron 1997, 53, 9541.
60. [60]
  Saihu, L.; Benjamin, L. Angew. Chem., Int .Ed. 2010, 49, 628.
61. [61]
  Wu, M.; Wang, B.; Wang, S. F.; Xia, C. G.; Sun, W. Org. Lett. 2009, 11, 3622.
62. [62]
  Wang, B.; Miao, C. X.; Wang, S. F.; Xia, C. G.; Sun, W. Chem. Eur. J. 2012, 18, 6750.
63. [63]
  Wang, X.; Miao, C. X.; Wang, S. F.; Xia, C. G.; Sun, W. ChemCatchem 2013, 5, 2489.
64. [64]
  Shen, D. Y.; Miao, C. X.; Wang, S. F.; Xia, C. G.; Sun, W. Eur. J. Inorg. Chem. 2014, 33, 5777.
65. [65]
  Miao, C. X.; Wang, Bin.; Wang, Y.; Xia, C. G.; Lee,Y. M.; Nam, W.; Sun, W. J. Am. Chem. Soc. 2016, 138, 936.
66. [66]
  Shen, D. Y.; Qiu, B.; Xu, D. Q, Miao, C. X.; Xia, C. G.; Sun, W. Org. Lett. 2016, 18, 372.
67. [67]
  Bagherzadeh, M.; Latifi, R.; Tahsini, L. J. Mol. Catal. A: Chem. 2006, 260, 163.
68. [68]
  Zhong, S.; Tan, Y.; Fu, Z.; Xie, Q.; Xie, F.; Zhou, X.; Ye, Z.; Peng, G.; Yin, D. J. Catal. 2008, 256, 154.
69. [69]
  Ruffo, F.; Bismuto, A.; Carpentieri, A.; Cucciolito, M. E.; Lega, M. Inorg. Chim. Acta 2013, 405, 288.
70. [70]
  Amato, M. E.; Ballistreri, F. P.; Pappalardo, A.; Tomaselli, G. A.; Toscano, R. M.; Williams, D. J. Eur. J. Org. Chem. 2005, 3562.
71. [71]
  Suresh, P.; Srimurugan, S.; Dere, T. D.; Ragavan, R. V.; Gopinath, V. S. Tetrahedron: Asymmetry 2013, 24, 669.
72. [72]
  Erdem, O.; Guzel, B. Inorg. Chim. Acta 2014, 418, 153.
73. [73]
  Irie, R.; Noda, K.; Ito, Y.; Matsumoto, N.; Katsuki, T. Tetrahedron Lett. 1990, 31, 7345.
74. [74]
  Katsuki, T. Synlett 2003, 281.
75. [75]
  Chen, L. H.; Cheng, F. X.; Jia, L.; Zhang, A. J.; Wu, J. C.; Tang, N. Chirality 2011, 23, 69.
76. [76]
  Luo, R. C.; Tan, R.; Peng, Z. G.; Zhang, W. G.; Kong, Y.; Yin, D. H. J. Catal. 2012, 287, 170.
77. [77]
  Borriello, C.; Litto, R. D.; Panunzi, A.; Ruffo, F. Tetrahedron: Asymmetry 2004, 15, 681.
78. [78]
  Zhao, S. S.; Zhao, J. Q.; Zhao, D. M. Carbohydr. Res. 2007, 342, 254.
79. [79]
  Huang, X. M.; Fu, X. K.; Wu, X. J.; Jia, Z. Y. Tetrahedron Lett. 2013, 54, 4041.
80. [80]
  Solati, Z.; Hashemi, M.; Ebrahimi, L. Catal. Lett. 2011, 141, 163.
81. [81]
  Bendix, J.; Meyer, K.; Weyhermuller, T.; Bill, E.; Metzler-Nolte, N.; Wieghardt, K. Inorg. Chem. 1998, 37, 1767.
82. [82]
  Bosch, I. G.; Gómez, L.; Polo, A.; Ribas, X.; Costas, M. Adv. Synth. Catal. 2012, 354, 65.
83. [83]
  Lyakin, O.Y.; Ottenbacher, R. V.; Bryliakov, K. P.; Talsi, E. P. ACS Catal. 2012, 2, 1196.
84. [84]
  Ottenbacher, R. V.; Samsonenko, D. G. Talsi, E. P.; Bryliakov, K. P. ACS Catal. 2014, 4, 1599.
85. [85]
  Mcgarrigle, E. M.; Gilheany, D. G. Chem. Rev. 2005, 105, 1563
86. [86]
87. [87]
88. [88]
  Norrby, P. O.; Linde, C.; kermark, B. J. Am. Chem. Soc. 1995, 117, 11035.
89. [89]
  Backvall, J. E.; Bokman, F.; Blomberg, M. R. A. J. Am. Chem. Soc. 1992, 114, 534.
90. [90]
  Adam, W.; Mock, K. C.; Saha, M. C. R.; Herderich, M. J. Am. Chem. Soc. 2000, 122, 9685.
91. [91]
92. [92]
93. [93]
  Fraile, J. M.; Garci, J. I.; Mayoral, J. A. Chem Rev. 2009, 109, 360.
94. [94]
  Sellner, H.; Kajalainen, J. K.; Seebach, D. Chem. Eur. J. 2001, 7, 2873.
95. [95]
  Paucki, M.; Pospisil, P. J.; Zhang, W.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 9333.
96. [96]
  Kureshy, R. I.; Ahamd, I.; Khan, N. H.; Abdi, S. H. R.; Singh, S.; Pandia, P. H.; Jasram, R. V. J. Catal. 2005, 235, 28.
97. [97]
98. [98]
99. [99]
  Jacobsen, E. N.; Zhang, W.; Muci, A. R.; Ecker, J. R.; Deng, L. J. Am. Chem. Soc. 1991, 113, 7063.
100. [100]
  Hosoya, N.; Hatayama, A.; Irie, R.; Sasaki, H.; Katsuki, T. Tetrahedron 1994, 50, 4311.
101. [101]
  Rao, C. N. R.; Natarajan, S.; Neeraj, S. J. Solid State Chem. 2000, 152, 302.
102. [102]
  Thomas, J. M.; Raja, R.; Sankar, G. Nature 1999, 398, 227.
103. [103]
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