Citation: Xu Jian, Song Qiuling. Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds in the Presence of Dioxygen[J]. Chinese Journal of Organic Chemistry, ;2016, 36(6): 1151-1162. doi: 10.6023/cjoc201603042 shu

Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds in the Presence of Dioxygen

Xu Jian ^a ,
Song Qiuling ^a,b,*,,

a.
Institute of Next Generation Matter Transformation, College of Chemical Engineering, Huaqiao University, Xiamen 361021
b.
National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Siences, Beijing 100190

Corresponding author: Song Qiuling, qsong@hqu.edu.cn
Received Date: 2 January 2016
Revised Date: 20 January 2016

Fund Project: the Recruitment Program of Global Experts (1000 Talents Plan), the Fujian Hundred Talents Plan and the Program of Innovative Research Team of Huaqiao University No. Z14X0047Project supported by the National Natural Science Foundation of China No.21202049

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The difunctionalization of unsaturated carbon-carbon bonds is a powerful strategy for the synthesis of various organic compounds. Recently, the remarkable progress has been made in difunctionalization of unsaturated carbon-carbon bonds with dioxygen and radicals. The present protocol, which utilizes dioxygen as oxygen source, provides a green and atom economy approach to alcohols or ketones. This review will summarize the recent development in this area on the basis of different types of radicals.
- radical,
- difunctionalization,
- olefin,
- alkyne
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