Citation: Zeng Fei, Tang Linli, Chen Xiaoming, Li Zhizhang, Han Ying, Chen Chuanfeng. Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1937-1941. doi: 10.6023/cjoc201603024 shu

Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

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  • The complexation between the novel water-soluble cylindrical macrotricyclic host and paraquat guests in both solution and solid state was investigated in detail. It was found that the host could form 1:1 complexes with paraquat salts in water solution and solid state. Interestingly, the complexation and decomplexation of the complexes between the host and the guest could be achieved by changing the pH of the solution, and the process could also be observed by naked eye.
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    1. [1]

      Pedersen, C. J. J. Am. Chem. Soc. 1967, 89, 7017. 

    2. [2]

    3. [3]

       

    4. [4]

       

    5. [5]

      Corbellini, F.; Knegtel, R. M.; Grootenhuis, P. D.; Crego-Cala- ma, M.; Reinhoudt, D. N. Chem. Eur. J. 2004, 11, 298. (b) Liu, Y.; Guo, D.-S.; Yang, E.-C.; Zhang, H.-Y.; Zhao, Y.-L. Eur. J. Org. Chem. 2005, 2005, 162. (c) Guo, D. S.; Wang, K.; Wang, Y. X.; Liu, Y. J. Am. Chem. Soc. 2012, 134, 10244. (d) Kulasekharan, R.; Ramamurthy, V. Org. Lett. 2011, 13, 5092. (e) Tu, C.; Zhu, L.; Li, P.; Chen, Y.; Su, Y.; Yan, D.; Zhu, X.; Zhou, G. Chem. Commun. 2011, 47, 6063. (f) Specht, A.; Bernard, P.; Goeldner, M.; Peng, L. Angew. Chem., Int. Ed. 2002, 41, 4706.

    6. [6]

      Li, Z.; Yang, J.; Yu, G.; He, J.; Abliz, Z.; Huang, F. Chem. Commun. 2014, 50, 2841. (b) Si, W.; Chen, L.; Hu, X. B.; Tang, G.; Chen, Z.; Hou, J. L.; Li, Z. T. Angew. Chem., Int. Ed. 2011, 50, 12564. (c) Yu, G.; Xue, M.; Zhang, Z.; Li, J.; Han, C.; Huang, F. J. Am. Chem. Soc. 2012, 134, 13248. (d) Ma, Y.; Ji, X.; Xiang, F.; Chi, X.; Han, C.; He, J.; Abliz, Z.; Chen, W.; Huang, F. Chem. Commun. 2011, 47, 12340. (e) Chen, H.; Fan, J.; Hu, X.; Ma, J.; Wang, S.; Li, J.; Yu, Y.; Jia, X.; Li, C. Chem. Sci. 2015, 6, 197. (f) Ma, J.; Deng, H.; Ma, S.; Li, J.; Jia, X.; Li. C. Chem. Commun. 2015, 51, 6621.

    7. [7]

      Cram, D. J.; Cram, J. M. Science 1974, 183, 803. (b) Wei, P.; Yan, X.; Huang, F. Chem. Soc. Rev. 2015, 44, 815. (c) Chen, C.-F. Chem. Commun. 2011, 47, 1674. (d) Jiang, Y.; Chen, C.-F. Eur. J. Org. Chem. 2011, 6377. (e) Han, Y.; Meng, Z.; Ma, Y.-X.; Chen, C.-F. Acc. Chem. Res. 2014, 47, 2026. 

    8. [8]

      Hoffart, D. J.; Tiburcio, J.; de la Torre, A.; Knight, L. K.; Loeb, S. J. Angew. Chem., Int. Ed. 2008, 47, 97. (b) Chen, L.; Zhang, Y. M.; Liu, Y. J. Phys. Chem. B 2012, 116, 9500. (c) Chen, L.; Zhang, H. Y.; Liu, Y. J. Org. Chem. 2012, 77, 9766. (d) Ji, X.; Zhang, M.; Yan, X.; Li, J.; Huang, F. Chem. Commun. 2013, 49, 1178. 

    9. [9]

      Zeng, F.; Chen, C.-F. Org. Biomol. Chem. 2015, 13, 1988. 

    10. [10]

      Connors, K. A. Binding Constants, John-Wiley and Sons, New York, 1987.

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