Citation: Wang Lijun, Lau Choiwan, Xiong Juan, Hu Jinfeng. Further Chemical Constituents from the Rare Chloranthaceae Plant Chloranthus sessilifolius[J]. Chinese Journal of Organic Chemistry, ;2016, 36(7): 1677-1680. doi: 10.6023/cjoc201602002 shu

Further Chemical Constituents from the Rare Chloranthaceae Plant Chloranthus sessilifolius

1.
School of Pharmacy, Fudan University, Shanghai 201203

Corresponding author: Hu Jinfeng,
Received Date: 1 February 2016
Revised Date: 4 March 2016

Fund Project: National Natural Science Foundation of China 21472021National Natural Science Foundation of China 21575029the National Basic Research Program of China 2013CB530700the National Basic Research Program of China 973 ProgramNational Natural Science Foundation of China 81273401

Figures(2)

Two diterpenoids and a few miscellaneous components (one phenethylpropanoid, one flavonoid, and one lignan) were isolated from the MeOH extract of the whole plant of the rare Chloranthaceae plant Chloranthus sessilifolius during a further phytochemical reinvestigation. Based on their spectroscopic data (i.e., IR, UV, 1D/2D NMR, ECD, and HR-ESIMS) and/or comparing with those reported physicochemical data in related literature, the structures were determined to be (3R, 5S, 6S, 9S, 10S, 13S)-3, 6, 13-trihydroxy-ent-abieta-8(14)-en-7-one (1), 3α, 15-dihydroxy-13α-methoxy-ent-abieta-8(14)-en-7-one (2), p-coumaroyl-β-phenethyl amine (3), narigenin trimethyl ether (4), and (3R, 4R, 3'R, 4'R)-6, 6'-dimethoxy-3, 4, 3', 4'-tetrahydro-2H, 2H'-[3, 3']-bichromenyl-4, 4'-diol (5). Among them, compound 1 is new, while compounds 3~5 were isolated from the Chloranthus genus for the first time.
- Chloranthus sessilifolius,
- Chloranthaceae,
- chemical constituents,
- ent-abietane-type diterpenoids
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