Citation: Liu Jinbiao, Yuan Sitian, Song Xixi, Qiu Guanyinsheng. Recent Advances in the Coupling Reactions of Arylhydrazine via C—N Bond Cleavage[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1790-1796. doi: 10.6023/cjoc201601037 shu

Recent Advances in the Coupling Reactions of Arylhydrazine via C—N Bond Cleavage

Liu Jinbiao ^a,*,, ,
Yuan Sitian ^a ,
Song Xixi ^b ,
Qiu Guanyinsheng ^b,*,,

a.
School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000
b.
College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001

Corresponding author: Liu Jinbiao, liujbgood@hotmail.com Qiu Guanyinsheng, qiuguanyinsheng@mail.zjxu.edu.cn
Received Date: 28 January 2016
Revised Date: 15 April 2016

Fund Project: Project supported by the National Natural Science Foundation of China Nos. 21502075，21502069，201502069the National Natural Science Foundation of Zhejiang Province No. LQ15B020006and the Foundation from Zhejiang Education Department No. Y201431173

Figures(11)

As a special synthons containing C—N bond, hydrazine chemistry has attracted a growing interest of chemists due to its versatility in cross-coupling arylation. This review summarizes the recent advances in the coupling reactions of arylhydrazine, which is utilized as an effective arylation reagent in radical reactions, and transition metal-catalyzed homocoupling, Suzuki coupling and Heck coupling via C—N bond cleavage.
- C—N bond cleavage,
- aryl hydrazine,
- coupling reaction,
- radical
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