Citation: Bi Cheng, Xiong Xingquan, Shi Lin, Xiao Shangyun. Highly Efficient and Green Synthesis of Propargylic Amines Catalyzed by Waste Crab Shell Powders-Supported CuI Catalyst[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1847-1853. doi: 10.6023/cjoc201601021 shu

Highly Efficient and Green Synthesis of Propargylic Amines Catalyzed by Waste Crab Shell Powders-Supported CuI Catalyst

1.
Key Laboratory for Functional Materials of Fujian Higher Education, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021

Corresponding author: Xiong Xingquan, xxqluli@hqu.edu.cn
Received Date: 18 January 2016
Revised Date: 10 April 2016

Fund Project: the Natural Science Foundation of Fujian Province (No.2016J01063), the Program for New Century Excellent Talents in Fujian Province No.2016J01063the University Distinguished Young Research Talent Training Program of Fujian Province No. 11FJPY02and the Promotion Program for Young and Middle-Aged Teacher in Science and Technology Research of Huaqiao University No. ZQN-YX103Project supported by the National Natural Science Foundation of China No. 21004024the Program for New Century Excellent Talents in Fujian Province No. 2012FJ-NCET-ZR03

Figures(4)

A series of propargylic amines were synthesized from terminal alkynes, dichloromethane and organic amines by using waste crab shell powders supported-CuI (CSPs-CuI) as catalyst. Using waste crab shell powders as catalyst support, not only resolve the problem of environment pollution and resources waste, but also produce propargylic amines through a highly efficient and green method. CSPs-CuI was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TG) and atomic absorption spectroscopy (AAS). The reaction conditions were optimized by the investigation of catalyst support and base types. The propargyllic amines were obtained readily in intermediate to excellent yields under the optimal reaction condition. CSPs-CuI showed good reusability and could be recovered easily through filtration and washing. It was reused at least 4 times without obvious loss of catalytic performance.
- propargylic amines,
- crab shell powders,
- copper catalysis,
- heterogeneous catalyst,
- green synthesis,
- three-component reaction
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沈阳化工大学材料科学与工程学院沈阳 110142