Citation: Zhou Peng, Qiu Huihua, Pan Hongcheng, Shi Jicheng, Zhou Jianmin. Researches on the α-Aminoxylation between α-Azoleketones and 2,2,6,6-Tetramethylpiperidine-1-oxyl with Cu/O₂[J]. Chinese Journal of Organic Chemistry, ;2016, 36(7): 1596-1601. doi: 10.6023/cjoc201601019 shu

Researches on the α-Aminoxylation between α-Azoleketones and 2,2,6,6-Tetramethylpiperidine-1-oxyl with Cu/O₂

1.
School of Chemical engineering, Guangdong University of Petrochemical Technology, Maoming, 525000

Corresponding author: Zhou Peng, zhoupeng@gdupt.edu.cn
Received Date: 15 January 2016
Revised Date: 16 March 2016

Fund Project: the Guangdong University of Petrochemical Technology No. 2015DCA037the National Natural Science Foundation of China No. 21272037the Natural Science Foundation of Guangdong Province No. S2013040014944

Figures(1)

The α-aminoxylation between α-azoleketones and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied in this paper. Taking Cu(Ⅱ) salts as catalyst and air as oxidant, a number of alkoxyamines have been synthesized via α-aminoxylation between α-azoleketones and TEMPO in good yields at room temperature. This strategy is highlighted by appealing features such as mild reaction condition, inexpensive catalyst, green oxidant and good yield.
- Cu catalyzed,
- dioxygen,
- α-azoleketone,
- 2,2,6,6-tetramethylpiperidine-1-oxyl,
- α-aminoxylation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Researches on the α-Aminoxylation between α-Azoleketones and 2,2,6,6-Tetramethylpiperidine-1-oxyl with Cu/O2

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通讯作者: 陈斌, bchen63@163.com

Researches on the α-Aminoxylation between α-Azoleketones and 2,2,6,6-Tetramethylpiperidine-1-oxyl with Cu/O₂