Citation: Li Wenfang, Zhu Junyan, Dong Zeyuan. Synthesis of Hollow Aromatic Helix and Their Selective Recognition for Alkali Metal Ions[J]. Chinese Journal of Organic Chemistry, ;2016, 36(7): 1668-1671. doi: 10.6023/cjoc201601004 shu

Synthesis of Hollow Aromatic Helix and Their Selective Recognition for Alkali Metal Ions

1.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012

Corresponding author: Dong Zeyuan,
Received Date: 4 January 2016
Revised Date: 9 May 2016

Fund Project: the National Natural Science Foundation of China 21274051the National Natural Science Foundation of China 21574054

Figures(4)

A novel type of hollow aromatic helices was prepared according to an improved organic synthesis approach. By means of UV-Vis spectroscopy, the recognition and selectivity of aromatic helix (AH) for alkali metal ions were investigated. The results indicated that AH could specifically recognize the alkali metal ions with an order of Rb⁺ > K⁺ > Cs⁺ > Na⁺ > Li⁺. In addition, the fluorescence titration was carried out by adding Rb⁺ into the AH solution, which further underpinned the binding capacity and sensitive responsiveness of AH for the alkali metal ions.
- aromatic helix,
- hollow channel,
- alkali metal ions,
- selective recognition
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